899820-34-9Relevant academic research and scientific papers
Fluoride-induced nucleophilic (phenylthio)difluoromethylation of carbonyl compounds with [difluoro(phenylthio)methyl]trimethylsilane (TMS-CF 2SPh)
Prakash, G.K. Surya,Hu, Jinbo,Wang, Ying,Olah, George A.
, p. 529 - 534 (2005)
A fluoride-induced nucleophilic (phenylthio)difluoromethylation method using TMS-CF2SPh has been achieved. This new methodology efficiently transfers "PhSCF2" group into both enolizable and non-enolizable aldehydes and ketones to giv
α,α-Difluoro-α-phenylsulfanylmethyl carbanion equivalent: a novel gem-difluoromethylenation of carbonyl compounds
Pohmakotr, Manat,Boonkitpattarakul, Kanhokthron,Ieawsuwan, Winai,Jarussophon, Suwatchai,Duangdee, Nongnaphat,Tuchinda, Patoomratana,Reutrakul, Vichai
, p. 5973 - 5985 (2007/10/03)
α,α-Difluoro-α-phenylsulfanyl-α-trimethylsilylmethane (PhSCF2SiMe3) has been demonstrated as an α,α-difluoro-α-phenylsulfanylmethyl carbanion equivalent. gem-Difluorophenylsulfanylmethylation of carbonyl compounds has been successful
