900187-89-5Relevant academic research and scientific papers
Oxazolidinones and 2,5-Dihydrofurans via Zinc-Catalyzed Regioselective Allenylation Reactions of l -α-Amino Aldehydes
Zamani, Farzad,Pyne, Stephen G.,Hyland, Christopher J. T.
, p. 6819 - 6830 (2017/07/17)
The simultaneous control of diastereoselectivity and regioselectivity in Zn-catalyzed allenylation reactions of N-protected l-α-amino aldehydes is reported. A reversal in diastereoselectivity could be realized by variation of the α-amino aldehyde protecti
Highly diastereoselective epimerization: Stereodivergent synthesis of α-hydroxy-β-amino isopentanoic acid
Seo, Woo Duck,Curtis-Long, Marcus J.,Ryu, Young Bae,Lee, Jin Hwan,Yang, Min Suk,Lee, Woo Song,Park, Ki Hun
, p. 5008 - 5011 (2007/10/03)
The high diastereoselectivity of the base-catalyzed epimerization of oxazolidin-2-ones 7 and 8 is shown to depend on the nature of the N-substituent (R group); when R = Bn, the 4,5-trans-product (4S,5R)-9 is formed, whereas when R = H the 4,5-cis-product
