90147-73-2

Basic information

• Product Name: ethyl 4-oxo-6-phenylhexanoate
• Synonyms: ethyl 4-oxo-6-phenylhexanoate
• CAS NO: 90147-73-2
• Molecular Weight: 234.295
• Mol File: 90147-73-2.mol
• Article Data: 12

Chemical Properties

• CAS DataBase Reference: ethyl 4-oxo-6-phenylhexanoate(CAS DataBase Reference)
• NIST Chemistry Reference: ethyl 4-oxo-6-phenylhexanoate(90147-73-2)
• EPA Substance Registry System: ethyl 4-oxo-6-phenylhexanoate(90147-73-2)

Safety Data

• Hazardous Substances Data: 90147-73-2(Hazardous Substances Data)

Upstream product

• 14794-31-1 ethyl 3-(chloroformyl)propionate 
• 71760-01-5 Bis-(phenethyl)-cadmium 
• 121748-61-6 (E)-6,6-diethoxy-5-hydroxy-1-phenyl-4-hexen-3-one 
• 121748-60-5 6,6-diethoxy-5-hydroxy-1-phenyl-3-hexanone 
• 75-11-6 diiodomethane 
• 17071-29-3 ethyl 3-oxo-5-phenylpentanoate 
• 13122-67-3 6-phenyl-4-oxohexanoic acid 
• 75-03-6 ethyl iodide 
• 121748-58-1 ethyl (trans)-6-phenyl-4-oxo-5-hexenoate 
• 501-52-0 3-Phenylpropionic acid 
• 121748-59-2 5-(diethoxymethyl)-3-(E)-2-phenylethenyl-2-isoxazoline 
• 113847-96-4 5-(diethoxymethyl)-3-<(diethoxyphosphinyl)methyl>-2-isoxazoline 
• 911641-23-1 bis(2-carboethoxyethyl)zinc 
• 645-45-4 hydrocinnamic acid chloride 

Downstream Products

• 112607-22-4 (+)-(R)-5-(2-phenylethyl)dihydrofuran-2(3H)-one 
• 675589-40-9 (3R,7aS)-3-phenyl-7a-(2-phenylethyl)-2,3,7,7a-tetrahydropyrrolo[2,1-b]oxazol-5-one 
• 13122-67-3 6-phenyl-4-oxohexanoic acid 
• 2430-76-4 6-phenyl-1,4-hexanediol 

Relevant articles and documents

Palladium/Zinc Co-Catalyzed Asymmetric Hydrogenation of γ-Keto Carboxylic Acids

A palladium-catalyzed asymmetric hydrogenation of levulinic acid has been successful developed by using Zn(OTf)2 as co-catalyst. The present method not only has provided a strategy in the palladium-catalyzed asymmetric hydrogenation of ketone, but also allowed the preparation of a wide range of chiral γ-valerolactones in good yields with excellent enantioselectivities.

Preparation and Application of Amino Phosphine Ligands Bearing Spiro[indane-1,2′-pyrrolidine] Backbone

P,Nsp3-bidentate chiral ligands bearing spiro[indane-1,2′-pyrrolidine] backbone were prepared in gram scale for the first time. Pd complexes of these air-stable amino phosphine ligands could catalyze asymmetric allylic substitutions of malonate-, alcohol-, and amine-type nucleophiles in up to 97percent ee and 99percent yield. A crystal structure of [Pd(II)(η3-1,3-diphenylallyl)(ligand)]PF6 indicated possible transition states of the catalytic reactions. These ligands are characteristic of a very rigid backbone, which is simple but highly effective. They rival C2-symmetric bisphosphine, P,Nsp2-bidentate, and P,Nsp3-bidentate ligands in tested allylic substitutions. ?

Zinc-Mediated Conversion of β-Keto Esters to γ-Keto Esters

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