
Tetrahedron Letters p. 637 - 640 (1984)
Update date:2022-08-05
Topics:
Kauffmann, Thomas
Koenig, Rolf
Wensing, Michael
The reagents Ph3M-CH(I)Li (M=Si, Ge) react with benzaldehyde via anionic benzaldehyde adducts stereospecifically to give (Z)-1-phenyl-2-triphenylsilyl- (7a) or (Z)-1-phenyl-2-triphenylgermyl-oxirane (7b), respectively.By protolysis of the anionic benzaldehyde adducts at -65 deg C corresponding iodohydrins (5a,5b) have been obtained.
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