90546-12-6

Upstream product

• 82873-73-2 (2aS,4R,4aS,6aS,6bR)-2-Hydroxy-6,6-dimethyl-octahydro-pentaleno[1,6-bc]furan-4-carbaldehyde 
• 82873-75-4 (2aRS,4aSR,6aSR,6bRS)-2a,4a,5,6,6a,6b-hexahydro-6,6-dimethyl-2H-pentaleno<1,6-bc>furan-2-one 
• 69478-30-4 (1R,3aS,6aR)-2,2,6-Trimethyl-1,2,3,3a,4,6a-hexahydro-pentalen-1-ol 
• 90546-11-5 (3aRS,6SR,6aRS)-1-chloromethyl-3,3a,4,5,6,6a-hexahydro-6-hydroxy-5,5-dimethylpentalene 
• 69478-28-0 (1R,3aR,6aS)-6-Hydroxymethyl-2,2-dimethyl-1,2,3,3a,4,6a-hexahydro-pentalen-1-ol 
• 69478-30-4 (3aRS,6SR,6aRS)-3,3a,4,5,6,6a-hexahydro-6-hydroxy-1,5,5-trimethylpentalene 
• 82873-78-7 (3aRS,6SR,6aRS)-3,3a,4,5,6,6a-hexahydro-6-methanesulfonyloxy-1,5,5-trimethylpentalene 
• 90546-09-1 cis-3,3a,4,5,6,6a-hexahydro-5,5-dimethyl-6-oxo-1-pentalenecarboxylic acid methyl ester 
• 82873-74-3 (2aSR,4RS,4aSR,6aSR,6bRS)-octahydro-6,6-dimethyl-2-oxo-2H-pentaleno<1,6-bc>furan-4-carboxylic acid 
• 82873-76-5 (3aRS,6SR,6aRS)-3,3a,4,5,6,6a-hexahydro-6-hydroxy-5,5-dimethyl-1-pentalenecarboxylic acid methyl ester 
• 98-88-4 benzoyl chloride 

Downstream Products

• 82881-09-2 6α-benzoyloxy-4β,7,7-trimethyl-1α,5α-bicyclo<3.3.0>octan-3-one 
• 90546-13-7 (1RS,2RS,3aRS,6RS,6aRS)-6-benzoyloxy-octahydro-2-hydroxy-1,5,5-trimethylpentalene 
• 82873-81-2 (1SR,3aRS,6RS,6aRS)-6-benzoyloxy-1-(2-chloro-2-propenyl)-1,3a,4,5,6,6a-hexahydro-1,5,5-trimethyl-2(3H)-pentalenone 
• 82873-82-3 (1SR,3aRS,6RS,6aRS)-1-acetonyl-6-benzoyloxy-1,3a,4,5,6,6a-hexahydro-1,5,5-trimethyl-2(3H)-pentalenone 
• 85031-56-7 (3aR,3bS,4S,6aR,7R)-3,3a,5,5-Tetramethyl-3-phenylselanyl-4,7-bis-(tetrahydro-pyran-2-yloxy)-3,3a,3b,4,5,6,6a,7-octahydro-cyclopenta[a]pentalen-2-one 
• 82873-85-6 (3aR,3bS,4S,6aR,7R)-7-Hydroxy-3,3a,5,5-tetramethyl-3-phenylselanyl-4-(tetrahydro-pyran-2-yloxy)-3,3a,3b,4,5,6,6a,7-octahydro-cyclopenta[a]pentalen-2-one 

Relevant academic research and scientific papers

SYNTHESIS OF dl-CORIOLIN

The total synthesis of dl-coriolin has been achieved in a stereoselective way.The key tricyclic intermediate was synthesized from dicyclopentadiene through a route which involved an SN2 reaction at a neopentylic position.

A NEW SYNTHESIS OF dl-CORIOLIN A. APPLICATION OF A NEW SN2 REACTION AT A NEOPENTYLIC POSITION

Dicyclopentadiene has been stereoselectively converted to a key tricyclic intermediate for the total synthesis of coriolin, through a route which involves a new SN2 reaction at a neopentylic position.