90670-04-5

Basic information

• Product Name: Piperidine, 1-benzoyl-4-chloro-
• CAS NO: 90670-04-5
• Molecular Formula: C12H14ClNO
• Molecular Weight: 223.702
• Mol File: 90670-04-5.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: Piperidine, 1-benzoyl-4-chloro-(CAS DataBase Reference)
• NIST Chemistry Reference: Piperidine, 1-benzoyl-4-chloro-(90670-04-5)
• EPA Substance Registry System: Piperidine, 1-benzoyl-4-chloro-(90670-04-5)

Safety Data

• Hazardous Substances Data: 90670-04-5(Hazardous Substances Data)

Upstream product

• 5382-16-1 4-HYDROXYPIPERIDINE 
• 80213-01-0 (4-hydroxy-1-piperidinyl)(phenyl)methanone 
• 98-88-4 benzoyl chloride 
• 5274-99-7 1-benzoylisonipecotic acid 
• 3725-39-1 N-(cylododec-1-enyl)-morpholine 
• 107264-22-2 C₂₆H₂₄N₂O₃ 
• 90670-03-4 N-Benzoyl-4-piperidinopiperidine 
• 58748-24-6 N-Cyclododecylmorpholine 

Relevant articles and documents

Frustrated Lewis Pair Catalyzed Hydrogenation of Amides: Halides as Active Lewis Base in the Metal-Free Hydrogen Activation

A method for the metal-free reduction of carboxylic amides using oxalyl chloride as an activating agent and hydrogen as the final reductant is introduced. The reaction proceeds via the hydrogen splitting by B(2,6-F2-C6H3)3 in combination with chloride as the Lewis base. Density functional theory calculations support the unprecedented role of halides as active Lewis base components in the frustrated Lewis pair mediated hydrogen activation. The reaction displays broad substrate scope for tertiary benzoic acid amides and α-branched carboxamides.

PHOTODECARBOXYLATIVE CHLORINATION OF CARBOXYLIC ACIDS VIA THEIR BENZOPHENONE OXIME ESTERS

Decarboxylative chlorination of various aromatic and aliphatic carboxylic acids is performed successfully by the photolysis of their benzophenone oxime esters in carbon tetrachloride and corresponding chloro compounds are prepared in good yields.High selective generation of the certain radical and efficiency of the stable radical precursor, benzophenone oxime ester, afford much advantage for radical chemistry.