91111-01-2

Basic information

• Product Name: (R)-1-oxo-1-phenylpropan-2-yl acetate
• Synonyms: (R)-1-oxo-1-phenylpropan-2-yl acetate
• CAS NO: 91111-01-2
• Molecular Weight: 192.214
• Mol File: 91111-01-2.mol
• Article Data: 15

Chemical Properties

• CAS DataBase Reference: (R)-1-oxo-1-phenylpropan-2-yl acetate(CAS DataBase Reference)
• NIST Chemistry Reference: (R)-1-oxo-1-phenylpropan-2-yl acetate(91111-01-2)
• EPA Substance Registry System: (R)-1-oxo-1-phenylpropan-2-yl acetate(91111-01-2)

Safety Data

• Hazardous Substances Data: 91111-01-2(Hazardous Substances Data)

Upstream product

• 100-59-4 phenylmagnesium chloride 
• 36394-75-9 (S)-2-acetoxypropanoyl chloride 
• 591-51-5 phenyllithium 
• 100-58-3 phenylmagnesium bromide 
• 535-17-1 (S)-2-acetoxypropionic acid 
• 2114-00-3 2-bromo-1-phenyl-1-propanone 
• 13266-91-6 (Z)-1-phenylprop-1-en-1-yl acetate 
• 64-19-7 acetic acid 
• 93-55-0 1-phenyl-propan-1-one 
• 1443215-57-3 3-oxo-3-phenylprop-1-en-2-yl acetate 
• 579-07-7 1-Phenylpropane-1,2-dione 
• 6493-83-0 2-methoxy-1-phenyl-propan-1-one 
• 5650-40-8 2-hydroxypropiophenone 
• 19347-08-1 acetic acid 1-methyl-2-oxo-2-phenyl-ethyl ester 

Downstream Products

• 5650-40-8 (S)-2-hydroxypropiophenone 
• 19347-08-1 acetic acid 1-methyl-2-oxo-2-phenyl-ethyl ester 
• 5650-40-8 2-hydroxypropiophenone 
• 88196-06-9 syn-1-phenylpropane-1,2-diol 
• 40421-52-1 (1RS,2SR)-1-phenylpropane-1,2-diol 
• 88196-06-9 (1S,2S)-1-phenyl-1,2-propanediol 
• 40421-52-1 (1R,2S)-1-phenylpropane-1,2-diol 

Relevant articles and documents

Hypervalent Iodine(III)-Catalysed Enantioselective α-Acetoxylation of Ketones

An enantioselective catalytic synthesis of α-acetoxylated ketones through I(I)/I(III) catalysis using a resorcinol/lactamide-based chiral iodoarene is reported. Catalyst turnover by in situ generation of the active iodine(III) derivative is achieved by oxidation with mCPBA in the presence of acetic acid. The prior transformation of ketones to easily accessible acetyl enol ethers is beneficial and yields up to 97 percent with enantioselectivities up to 88 percent ee are obtained using only low catalyst loadings of only 5 mol percent under mild reaction conditions.

Palladium-Catalyzed Oxidative Synthesis of α-Acetoxylated Enones from Alkynes

We report a palladium-catalyzed oxidative functionalization of alkynes to generate α-acetoxylated enones in one step. A range of functional groups are well-tolerated in this reaction. Mechanistic studies, including the use of 18O-labeled DMSO,

NMR determination of absolute configuration of α-acyloxy ketones

Determination of the absolute configuration of several acyclic α-acyloxy-ketones, and δ-ketobutanolides, in the presence of a chiral solvating agent, by low temperature and low concentration 1H NMR analysis, is reported.