911372-48-0

Basic information

• Product Name: (R_S)-N-(1-(4-bromophenyl)ethylidene)-2-methylpropane-2-sulfinamide
• Synonyms: (R_S)-N-(1-(4-bromophenyl)ethylidene)-2-methylpropane-2-sulfinamide
• CAS NO: 911372-48-0
• Molecular Weight: 302.235
• Mol File: 911372-48-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (R_S)-N-(1-(4-bromophenyl)ethylidene)-2-methylpropane-2-sulfinamide(CAS DataBase Reference)
• NIST Chemistry Reference: (R_S)-N-(1-(4-bromophenyl)ethylidene)-2-methylpropane-2-sulfinamide(911372-48-0)
• EPA Substance Registry System: (R_S)-N-(1-(4-bromophenyl)ethylidene)-2-methylpropane-2-sulfinamide(911372-48-0)

Safety Data

• Hazardous Substances Data: 911372-48-0(Hazardous Substances Data)

Upstream product

• 99-90-1 para-bromoacetophenone 
• 196929-78-9 (R)-2-methylpropane-2-sulfinamide 

Downstream Products

• 1508278-98-5 C₂₅H₄₄BrNO₄SSi 
• 84499-77-4 (S)-α-(p-bromophenyl)ethylamine hydrochloride 
• 911372-67-3 (R_S)-N-((S)-1-(4-bromophenyl)ethyl)-2-methylpropane-2-sulfinamide 
• 911372-66-2 (R_S)-N-((R)-1-(4-bromophenyl)ethyl)-2-methylpropane-2-sulfinamide 

Relevant articles and documents

Reversal of diastereofacial selectivity in hydride reductions of N-tert-butanesulfinyl imines

A variety of N-tert-butanesulfinyl imines were reduced with NaBH 4 in THF containing 2% water to provide the corresponding secondary sulfinamides in high yield and diastereoselectivity. By using the same sulfinyl imine starting materials and changing the reductant to L-Selectride, the stereoselectivity could be efficiently reversed to afford the opposite product diastereomer in high yield and selectivity.