91214-21-0Relevant articles and documents
Iron-Catalyzed C(sp 3)-H Alkylation through Ligand-to-Metal Charge Transfer
Kang, Yi Cheng,Rovis, Tomislav,Treacy, Sean M.
supporting information, p. 1767 - 1771 (2021/08/20)
We report the FeCl 3-catalyzed alkylation of nonactivated C(sp 3)-H bonds. Photoinduced ligand-to-metal charge transfer at the iron center generates chlorine radicals that then preferentially abstract hydrogen atoms from electron-ric
Highly chemoselective, oxyvanadium-catalysed cleavage of α-hydroxy ketones
Kirihara, Masayuki,Takizawa, Shinobu,Momose, Takefumi
, p. 7 - 8 (2007/10/03)
α-Hydroxy ketones (α-ketols) can be cleaved chemoselectively with a catalytic amount of dichloroethoxyoxyvanadium under an oxygen atmosphere.