913256-71-0

Upstream product

• 1345116-40-6 C₁₁H₁₉NO₄ 
• 951163-64-7 tert-butyl [(1S,3R)-4-hydroxy-1-(hydroxymethyl)-3-methylbutyl]carbamate 
• 1345116-45-1 (S)-tert-butyl 4-((R)-3-(tert-butyldiphenylsilyloxy)-2-methylpropyl)-2,2-dimethyloxazolidine-3-carboxylate 
• 1345116-48-4 tert-butyl (2S,4R)-5-(tert-butyldiphenylsilyloxy)-1-hydroxy-4-methylpentan-2-ylcarbamate 
• 92817-88-4 (2S)-3-{[tert-butyl(diphenyl)silyl]oxy}-2-methylpropanal 
• 445483-91-0 (4S)-3-[(2S,4R)-2-azido-5-tert-butyldiphenylsilyloxy-4-methylpentanoyl]-4-phenyloxazolidin-2-one 
• 445483-90-9 (4S)-3-[(4R)-5-tert-butyldiphenylsilyloxy-4-methylpentanoyl]-4-phenyloxazolidin-2-one 
• 445483-89-6 (4S)-3-[(4R,2E)-5-tert-butyldiphenylsilyloxy-4-methyl-2-pentenoyl]-4-phenyloxazolidin-2-one 
• 58479-61-1 tert-butylchlorodiphenylsilane 
• 95514-03-7 (S)-3-(tert-butyl-diphenyl-silanyloxy)-2-methyl-propionic acid methyl ester 
• 445483-92-1 (4S)-3-[(2S,4R)-2-tert-butoxycarbonylamino-5-tert-butyldiphenylsilyloxy-4-methylpentanoyl]-4-phenyloxazolidin-2-one 

Downstream Products

• 913256-76-5 (2S,4R)-tert-butyl 2-tert-butoxycarbonylamino-5-tert-butyldiphenylsilyloxy-4-methylpentanoate 
• 913256-72-1 (2S,4R)-tert-butyl 2-[bis(tert-butoxycarbonyl)amino]-5-tert-butyldiphenylsilyloxy-4-methylpentanoate 
• 855315-44-5 (6S,9R,12S)-methyl 6-((R)-3-(benzoyloxy)-2-methylpropyl)-12-((R)-methoxy(phenyl)methyl)-2,2,5,9-tetramethyl-4,7,10-trioxo-3-oxa-5,8,11-triazatridecan-13-oate 
• 1345116-64-4 (6R,8S,11S,14S)-8-(tert-butoxycarbonyl(methyl)amino)-14-((R)-methoxy(phenyl)methyl)-2,2,6,11-tetramethyl-9,12-dioxo-3,3-diphenyl-4-oxa-10,13-diaza-3-silapentadecan-15-oic acid 
• 1345116-67-7 (6R,8S,11R,14S)-methyl 8-(tert-butoxycarbonyl(methyl)amino)-14-((R)-methoxy(phenyl)methyl)-2,2,6,11-tetramethyl-9,12-dioxo-3,3-diphenyl-4-oxa-10,13-diaza-3-silapentadecan-15-oate 
• 1027190-57-3 (6R,8S)-2,2,6,9,12,12-hexamethyl-10-oxo-3,3-diphenyl-4,11-dioxa-9-aza-3-silatridecane-8-carboxylic acid 

Relevant academic research and scientific papers

Synthesis of the 'southern' tripeptide of Cyclomarins A and C having novel anti-tuberculocidal mode of action

The synthesis of the 'southern' tripeptide of Cyclomarins A and C has been described which includes two unusual amino acids. The unusual amino acids have been synthesized and coupled with l-alanine to obtain the tripeptide.

Polychlorinated leucine derivatives: Synthesis of (2S,4R)-5,5- dichloroleucine and its J-based analysis

A total synthesis of (2S,4R)-5,5-dichloroleucine is reported in 13 steps from (S)-methyl 2-(hydroxymethyl)propanoate. A density functional J-based analysis of this compound and a comparison with that of its (2S,4S) epimer is also performed in order to com

Syntheses of four unusual amino acids, constituents of cyclomarin A

The stereoselective syntheses of four unusual amino acids, constituents of cyclomarin A, are described. The protected N-methylhydroxyleucine 2 was synthesized using Evans' asymmetric azide-transfer reaction. The unusual amino acid 3 was prepared via diastereoselective methylation of the L-aspartic acid derived lactone 13. The stereoselective formation of threo-β-methoxyphenylalanine 4 was performed via aldol reaction using Scho?llkopf's chiral glycine enolate. The synthesis of N-reverse prenylated tryptophane 5 was achieved by the AQN ligand-promoted Sharpless regioreversed asymmetric aminohydroxylation protocol.