91489-49-5

Basic information

• Product Name: benzoyl dimethyl phosphate
• Synonyms: benzoyl dimethyl phosphate
• CAS NO: 91489-49-5
• Molecular Weight: 230.157
• Mol File: 91489-49-5.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: benzoyl dimethyl phosphate(CAS DataBase Reference)
• NIST Chemistry Reference: benzoyl dimethyl phosphate(91489-49-5)
• EPA Substance Registry System: benzoyl dimethyl phosphate(91489-49-5)

Safety Data

• Hazardous Substances Data: 91489-49-5(Hazardous Substances Data)

Upstream product

• 512-56-1 trimethyl phosphite 
• 98-88-4 benzoyl chloride 
• 65-85-0 benzoic acid 
• 813-77-4 Dimethyl chlorophosphate 
• 32586-82-6 sodium dimethyl phosphate 
• 29197-76-0 dimethyl iodophosphate 
• 868-85-9 Dimethyl phosphite 
• 756-77-4 tetramethylammonium dimethyl phosphate 
• 16965-72-3 dimethyl α-diazobenzylphosphonate 

Downstream Products

• 93-98-1 N-phenyl benzoyl amide 
• 1627963-01-2 2-benzamido-2-(hydroxymethyl)-4-(4-octylphenyl)butyl acetate 
• 1627962-97-3 2-benzamido-2-(hydroxymethyl)-4-(4-octylphenyl)butylbenzoate 
• 40948-30-9 N-(3-dimethylaminopropyl)benzamide 
• 18048-90-3 (1R,2R)-2-benzoylamino-1-(4-nitro-phenyl)-propane-1,3-diol 
• 690-49-3 tetramethyl pyrophosphate 
• 93-97-0 benzoic acid anhydride 

Relevant articles and documents

Benzoyl methyl phosphates as efficient reagents in the one-pot tandem approach for the synthesis of 2-phenylbenzimidazoles in water

A novel and efficient method for the environmentally benign, catalyst- and auxiliary-free synthesis of 2-phenylbenzimidazoles in water is developed. Benzoyl methyl phosphates play important roles as biomimetic acylating agents for the one-pot tandem approach without additional catalysts.

An efficient protocol for the amidation of carboxylic acids promoted by trimethyl phosphite and iodine

A practical, one-pot protocol is described for the conversion of carboxylic acids into amides through carboxyl activation by the reagent combination of trimethyl phosphite and iodine. This method integrates several advantages: (1) it allows amines to be chemoselectively acylated with excellent results in the presence of sulfur and oxygen nucleophiles; (2) the method shows wide generality in respect of solvent, base, and substrate; (3) the reagents used are widely available and much less expensive than common coupling reagents, and (4) the process is remarkably convenient, permitting extraction, recrystallization, and column chromatography as optional work-up procedures. The chemoselectivity and generality of the method, the low cost, and wide availability of reagents combined with the ease of use make it a very favorable process.

Preparation of esters and amides from carboxylic acids by activation with dialkyl phosphite-carbon tetrachloride mixture

A simple one pot phase transfer catalytic method is described for the synthesis of carboxylic amides and esters from carboxylic acids and amines or alcohols, respectively. For the activation of the carboxylic acids 'in situ' generated phosphoric acid diester chlorides were applied.