91528-99-3

Basic information

• Product Name: tetraphenylphosphonium dioxotrichlororuthenate(VI)
• Synonyms: tetraphenylphosphonium dioxotrichlororuthenate(VI)
• CAS NO: 91528-99-3
• Molecular Weight: 578.824
• Mol File: 91528-99-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: tetraphenylphosphonium dioxotrichlororuthenate(VI)(CAS DataBase Reference)
• NIST Chemistry Reference: tetraphenylphosphonium dioxotrichlororuthenate(VI)(91528-99-3)
• EPA Substance Registry System: tetraphenylphosphonium dioxotrichlororuthenate(VI)(91528-99-3)

Safety Data

• Hazardous Substances Data: 91528-99-3(Hazardous Substances Data)

Upstream product

• 2001-45-8 tetraphenyl phosphonium chloride 

Downstream Products

• 930-68-7 cyclohexenone 
• 1561-86-0 2-chlorocyclohexanol 
• 286-20-4 cyclohexane-1,2-epoxide 
• 822-87-7 2-Chlorocyclohexanone 
• 719-22-2 2,6-Di-tert-butyl-1,4-benzoquinone 
• 2455-14-3 3,5,3',5'-tetra-tert-butyl-4,4'-diphenoquinone 
• 791-28-6 Triphenylphosphine oxide 
• 10311-08-7 dimethyl(phenyl)phosphine oxide 

Relevant articles and documents

Oxo Complexes of Ruthenium(VI) and (VII) as Organic Oxidants

Oxidation of a variety of saturated and unsaturated primary and secondary alcohols by tetraoxoruthenate(VI), 2-, tetraoxoruthenate(VII), -, barium trans-trioxodihydroxoruthenium(VI), trans-Ba, dioxotrichlororuthenate(VI), -, and dioxodichlorobipyridylruthenate(VI),, has been studied; 2- may be used catalytically in conjunction with 2- under basic aqueous conditions.For some of these systems, the oxidation of several aldehydes and amines were also examined.Both 2- and - oxidise primary alcohols to carboxylic acids and secondary alcohols to ketones; the reactivity of these reagents towards unsaturated alcohols was studied in particular.The new species and also cleanly oxidise a wide range of alcohols to aldehydes and ketones without attack of double bonds.Ba functions as a heterogeneous oxidant in dichloromethane, oxidising only the most reactive alcohols to aldehydes.