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1561-86-0

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1561-86-0 Usage

Chemical Properties

CLEAR COLOURLESS TO LIGHT YELLOW LIQUID

Check Digit Verification of cas no

The CAS Registry Mumber 1561-86-0 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 1,5,6 and 1 respectively; the second part has 2 digits, 8 and 6 respectively.
Calculate Digit Verification of CAS Registry Number 1561-86:
(6*1)+(5*5)+(4*6)+(3*1)+(2*8)+(1*6)=80
80 % 10 = 0
So 1561-86-0 is a valid CAS Registry Number.
InChI:InChI=1/C6H11ClO/c7-5-3-1-2-4-6(5)8/h5-6,8H,1-4H2/t5-,6+/m0/s1

1561-86-0SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 10, 2017

Revision Date: Aug 10, 2017

1.Identification

1.1 GHS Product identifier

Product name 2-CHLOROCYCLOHEXANOL

1.2 Other means of identification

Product number -
Other names Cyclohexene Chlorohydrin

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:1561-86-0 SDS

1561-86-0Relevant articles and documents

Kagan,J. et al.

, p. 343 - 344 (1977)

Lipase catalysed oxidations in a sugar-derived natural deep eutectic solvent

Vagnoni, Martina,Samorì, Chiara,Pirini, Daniele,Vasquez De Paz, Maria Katrina,Gidey, Dawit Gebremichael,Galletti, Paola

, (2021/05/06)

Chemoenzymatic oxidations involving the CAL-B/H2O2 system was developed in a sugar derived Natural Deep Eutectic Solvent (NaDES) composed by a mixture of glucose, fructose and sucrose. Good to excellent conversions of substrates like cyclooctene, limonene, oleic acid and stilbene to their corresponding epoxides, cyclohexanone to its corresponding lactone and 2-phenylacetophenone to its corresponding ester, demonstrate the viability of the sugar NaDES as a reaction medium for epoxidation and Baeyer-Villiger oxidation.

Method for preparing o-chlorocyclohexanone by using cyclohexanone by-product lightweight oil

-

Paragraph 0016; 0017; 0018; 0019; 0020, (2018/04/01)

The invention discloses a method for preparing o-chlorocyclohexanone through lightweight oil, wherein the lightweight oil is the by-product obtained from cyclohexanone preparation through oxidation ofcyclohexane, and the o-chlorocyclohexanone is prepared in the presence of an auxiliary agent and a catalyst by completely utilizing the cyclohexene oxide in the lightweight oil through ring opening,oxidation and other reactions. According to the present invention, with the method, the disadvantages of more impurities, harsh reaction condition or complex product purification and the like in the prior art are solved. The method comprises: in the presence of an auxiliary agent, carrying out a reaction on lightweight oil containing 1 mole of cyclohexene oxide and 1-2 moles of a hydrogen chloridesolution for 1-4 h at a temperature of 10-60 DEG C to generate 2-chlorocyclohexanol, distilling to remove the relatively low boiling point components to obtain high-purity 2-chlorocyclohexanol, carrying out a reaction on the high-purity 2-chlorocyclohexanol as a raw material and a certain amount of an oxidizing agent, washing, separating, rectifying, and collecting the distillate at a temperatureof 203-204 DEG C to obtain the o-chlorocyclohexanone with the purity of more than 99%, wherein the yield of the o-chlorocyclohexanone is more than 90%.

Chlorohydrination of allyl chloride with HCl and H2O2 catalyzed by hollow titanium silicate zeolite to produce dichloropropanol

Peng, Xinxin,Xia, Changjiu,Lin, Min,Yuan, Hui,Zhu, Bin,Zhang, Yao,Wang, Baorong,Shu, Xingtian

supporting information, p. 1221 - 1225 (2017/08/15)

Overall, over 95% of epichlorohydrin is industrially manufactured via the chlorohydrination route with hazardous Cl2 as a reagent, which brings serious operation and pollution problems. Herein, we describe a novel Cl2-free process for the synthesis of dichloropropanols from allyl chloride with H2O2 and HCl catalyzed by hollow titanium silicate zeolite under mild conditions. A high conversion and overall dichloropropanol selectivity exceeding 95% are simultaneously achieved, and the heterogeneous catalyst is highly stable and amenable for reuse. Comprehensive experimental and spectroscopic data suggest that the Lewis acidity of the framework Ti species has a synergistic effect with the Br?nsted acidity of HCl that promotes the epoxidation of allyl chloride and the ring opening of the epoxy groups.

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