915712-34-4

Basic information

• Product Name: (E)-Ethyl 2-(4-bromophenylimino)acetate
• Synonyms: (E)-Ethyl 2-(4-bromophenylimino)acetate;ethyl(E)-2-((4-bromophenyl)imino)acetate
• CAS NO: 915712-34-4
• Molecular Formula: C₁₀H₁₀BrNO₂
• Molecular Weight: 256.1
• Mol File: 915712-34-4.mol
• Article Data: 13

Chemical Properties

• Appearance: /
• CAS DataBase Reference: (E)-Ethyl 2-(4-bromophenylimino)acetate(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-Ethyl 2-(4-bromophenylimino)acetate(915712-34-4)
• EPA Substance Registry System: (E)-Ethyl 2-(4-bromophenylimino)acetate(915712-34-4)

Safety Data

• Hazardous Substances Data: 915712-34-4(Hazardous Substances Data)

Usage

General Description

(E)-ethyl 2-(4-bromophenylimino)acetate, also known as ethyl (E)-2-(4-bromophenylimino)acetate, is an organic compound with the chemical formula C11H12BrNO2. It is a light yellow liquid with a molecular weight of 277.12 g/mol. (E)-ethyl 2-(4-bromophenylimino)acetate is commonly used as an intermediate in the production of pharmaceuticals, agrochemicals, and dyes. It can also be used as a reagent in organic synthesis and as a building block for the preparation of various other compounds. (E)-ethyl 2-(4-bromophenylimino)acetate is known to have potential biological activity and is therefore of interest in medicinal research. Its unique chemical structure and properties make it a versatile and important compound in the field of organic chemistry.

Upstream product

• 2521-92-8 ethyl 2-((4-bromophenyl)amino)acetate 
• 6911-87-1 4-bromo-N-methylaniline 
• 109-94-4 formic acid ethyl ester 
• 924-44-7 glyoxylic acid ethyl ester 
• 106-40-1 4-bromo-aniline 

Downstream Products

• 1186321-38-9 ethyl 1,3-bis(4-bromophenyl)-4-methyl-5-oxoimidazolidine-2-carboxylate 
• 1097223-10-3 ethyl 1,3-bis(4-bromophenyl)-4-((4-bromophenyl)amino)-5-oxoimidazolidine-2-carboxylate 
• 1608150-23-7 ethyl (2S,4S,6S)-4,6-bis(1H-indol-3-yl)-1-(4-bromophenyl)piperidine-2-carboxylate 
• 1591680-46-4 ethyl 2-(4-bromophenylamino)-4-phenylbut-3-ynoate 
• 93-89-0 benzoic acid ethyl ester 

Relevant articles and documents

Multicomponent Approach to Hydantoins and Thiohydantoins Involving a Deep Eutectic Solvent

We report an efficient synthetic strategy to diverse hydantoins and thiohydantoins involving a three-component reaction with the aid of deep eutectic solvent. Here, N,N′-dimethyl urea and N,N′-dimethyl thiourea play a dual role as reactant and reaction medium along with l-(+)-tartaric acid. The three-component reaction provides an easy access to 5-amino-1,3-dialkyl-substituted hydantoins and thiohydantoins in good yields.

Polarity-Reversed Addition of Enol Ethers to Imines under Visible Light: Redox-Neutral Access to Azide-Containing Amino Acids

A three-component and polarity-reversed addition cascade with a glyoxylate-based imine, an enol ether, and TMSN3 was established for the construction of γ-azido amino acids under visible light. This transformation features mild and redox-neutra

Synthesis of Dihydrophenanthridines and Oxoimidazolidines from Anilines and Ethylglyoxylate via Aza Diels-Alder Reaction of Arynes and KF-Induced Annulation

The transition-metal-free multicomponent coupling of arynes, anilines, and ethylglyoxylate, proceeding via an inverse electron-demand aza Diels-Alder cycloaddition and N-arylation, has been demonstrated. This protocol allows rapid access to N-aryl dihydrophenanthridine derivatives in moderate to high yields at room temperature from readily available starting materials. In addition, an unprecedented fluoride induced annulation of ethyl(arylimino)acetates led to the formation of highly functionalized oxoimidazolidine derivatives in good yields under mild conditions.