91703-34-3

Basic information

• Product Name: Phenol, 2-(2,2-dibromoethenyl)-
• CAS NO: 91703-34-3
• Molecular Formula: C8H6Br2O
• Molecular Weight: 277.943
• Mol File: 91703-34-3.mol
• Article Data: 12

Chemical Properties

• CAS DataBase Reference: Phenol, 2-(2,2-dibromoethenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Phenol, 2-(2,2-dibromoethenyl)-(91703-34-3)
• EPA Substance Registry System: Phenol, 2-(2,2-dibromoethenyl)-(91703-34-3)

Safety Data

• Hazardous Substances Data: 91703-34-3(Hazardous Substances Data)

Upstream product

• 613-84-3 2-hydroxy-5-methylbenzaldehyde 
• 42867-45-8 (dibromomethylene)triphenylphosphorane 
• 90-02-8 salicylaldehyde 
• 135-02-4 ortho-anisaldehyde 
• 90585-32-3 1,1-dibromo-2-(2-methoxyphenyl)ethene 
• 558-13-4 carbon tetrabromide 

Downstream Products

• 271-89-6 1-benzofurane 
• 5101-44-0 2-ethynyl-phenol 
• 54008-77-4 2-bromo-1-benzofuran 
• 1309868-12-9 2-(benzofuran-2-yl)-5-(4-nitrophenyl)-oxazole 
• 1309868-11-8 2-(benzofuran-2-yl)-5-phenyloxazole 
• 94138-70-2 2-(benzofuran-2-yl)-5-phenyl-1,3,4-oxadiazole 
• 1309868-08-3 8-(benzofuran-2-yl)-7-benzyl-1,3-dimethylxanthine 
• 1309868-07-2 2-(benzofuran-2-yl)-5-(4-fluorophenyl)-oxazole 
• 1839-72-1 2-phenylbenzofuran 
• 25664-48-6 2-p-tolyl-benzofuran 
• 39195-66-9 2-(4-chlorophenyl)benzofuran 
• 65246-40-4 2‐(4‐tert‐butylphenyl)benzofuran 
• 19234-04-9 2-(p-methoxyphenyl)-benzo[b]furan 
• 787-64-4 2-(4-nitrophenyl)-1-benzofurane 

Relevant articles and documents

Palladium-Catalyzed Domino Cyclization/Phosphorylation of gem-Dibromoolefins with P(O)H Compounds: Synthesis of Phosphorylated Heteroaromatics

We presented a palladium-catalyzed domino cyclization/phosphorylation of gem-dibromoolefins, which utilize H-phosphinates and secondary phosphine oxides as the phosphine sources, respectively. A variety of phosphorylated heteroaromatics were obtained in m

Copper-catalyzed synthesis of 1-(2-benzofuryl)-N-heteroarenes fromo-hydroxy-gem-(dibromovinyl)benzenes and N-heteroarenes

An efficient method for the synthesis of 1-(2-benzofuryl)-N-heteroarenes is developed fromo-hydroxy-gem-(dibromovinyl)benzenes and N-heteroarenes under copper-catalyzed tandem reaction conditions. This methodology displayed a broad substrate scope and high yields in the preparation of a variety of 1-(2-benzofuryl)-N-heteroarenes. Further, 1-(2-benzofuryl)-N-heteroarenes were also applied in the synthesis of polycyclic benzofuro-indolo-pyridine scaffolds under palladium-catalyzed dehydrogenative coupling conditions. Overall, the present tandem approach is general, synthetically advantageous and avoids air-sensitive reagents.

Rapid Access to Benzofuran-Based Natural Products through a Concise Synthetic Strategy

A concise strategy is described for the synthesis of ailanthoidol (1), egonol (2), homoegonol (3), demethoxyegonol (4), demethoxyhomoegonol (5), and stemofuran A (6). This approach involves a Pd-catalysed domino cyclization/coupling process using triarylbismuth reagents for the generation of the benzofuran core. Subsequent structural modifications then give the final targets. The high yielding synthesis of the recently isolated natural products egonol-9(Z)-12(Z)-linoleate (2a), 7-demethoxyegonol-9(Z)-12(Z)-linoleate (4a), and 7-demethoxy-egonol-9(Z)-oleate (4b) are also reported.