92022-45-2

Basic information

• Product Name: Benzene, 1-bromo-4-[(phenylmethyl)sulfinyl]-
• CAS NO: 92022-45-2
• Molecular Formula: C13H11BrOS
• Molecular Weight: 295.2
• Mol File: 92022-45-2.mol
• Article Data: 23

Chemical Properties

• CAS DataBase Reference: Benzene, 1-bromo-4-[(phenylmethyl)sulfinyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-bromo-4-[(phenylmethyl)sulfinyl]-(92022-45-2)
• EPA Substance Registry System: Benzene, 1-bromo-4-[(phenylmethyl)sulfinyl]-(92022-45-2)

Safety Data

• Hazardous Substances Data: 92022-45-2(Hazardous Substances Data)

Upstream product

• 60142-30-5 1-bromo-4-(bromomethylsulfinyl)benzene 
• 98-80-6 phenylboronic acid 
• 108-88-3 toluene 
• 53136-21-3 1-benzylsulphanyl-4-bromobenzene 
• 100-44-7 benzyl chloride 
• 106-53-6 para-bromobenzenethiol 
• 221292-39-3 1-[(4-bromophenyl)sulfanyl]-2-(trimethylsilyl)ethane 
• 943722-51-8 1-[(4-bromophenyl)sulfinyl]-2-(trimethylsilyl)ethane 
• 100-39-0 benzyl bromide 

Downstream Products

• 53136-21-3 1-benzylsulphanyl-4-bromobenzene 
• 588-46-5 N-(phenylmethyl)acetamide 
• 1204678-13-6 (benzyl)(4-bromophenyl)(imino)-λ⁶-sulfanone 
• 100375-03-9 1-bromo-4-(phenylmethanesulfonyl)benzene 

Relevant articles and documents

Metal-free oxidative coupling of alkyl chlorides with thiols: An efficient access to sulfoxides

An efficient and step-economical access to sulfoxides from thiols and alkyl halides in the presence of I2O5 and DBU via direct oxidative couplings is described here. It is the first case that combined Williamson sulfide synthesis and subsequent sulfide oxidation into one step manipulation for sulfoxides preparation. This protocol features wide substrate scope, mild and metal-free conditons, the use of naturally abundant starting materials and avoidance of over-oxidation.

Synthesis and characterization of sulfamic acid supported on Fe3O4 nanoparticles: A green, versatile and magnetically separable acidic catalyst for oxidation reactions and Knoevenagel condensation

Sulfamic acid immobilized on diethylenetriamine functionalized Fe3O4 nanoparticles (SA-DETA-Fe3O4) was successfully prepared and characterized by X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), vibrating sample magnetometer (VSM), thermo gravimetric analysis (TGA), X-Ray diffraction (XRD) and scanning electron microscopy (SEM). The sulfamic acid was found as a magnetically separable and highly active catalyst for the oxidative coupling thiols, oxidation of sulfides. Furthermore, the SA-DETA-Fe3O4 showed the high catalytic activity in Knoevenagel condensation of aromatic aldehydes with active methylene compounds (malononitrile and ethyl cynoacetate). The nanosolid catalyst could be easily recovered by a simple magnetic separation and reused for many cycles without deterioration in catalytic activity.

Green route for selective gram-scale oxidation of sulfides using tungstate/triazine-based ionic liquid immobilized on magnetic nanoparticles as a phase-transfer heterogeneous catalyst

Tungstate ions were successfully loaded onto triazine-based ionic liquid-functionalized magnetic nanoparticles through an anion exchange process. The use of triazine core for creating ionic liquid led to the immobilization of high amounts of WO4/sub