92167-80-1Relevant articles and documents
A Novel Synthesis of Phosphonates from Diethyl (Trichloromethyl)phosphonate
Lowen, Gregory T.,Almond, Merrick R.
, p. 4548 - 4550 (1994)
Commercially available diethyl (1,1,1-trichloromethyl)phosphonate was reacted with aldehydes and ketones to generate (chlorovinyl)phosphonates in a single step.These intermediates could be hydrogenated in high yields to the corresponding saturated phospho
Le O,O-diethyltrimethylsilylchloromethylphosphonate α-lithie (C2H5O)2P(O)C(Cl)Si(CH3)3Li
Teulade, Marie-Paule,Savignac, Philippe
, p. 295 - 304 (2007/10/02)
Silylation of either chloromethyl- or trichloromethyl-phosphonate in the presence of excess n-BuLi leads to the quantitative generation of lithiated trimethylsilylchloromethylphosphonates.This stable type of anion can be protonated, deuterated or alkylate