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3167-63-3

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3167-63-3 Usage

Chemical Properties

Clear colorless to light yellow liquid

Uses

Reactant involved in:Subsequent alkylation after nucleophilic substitutionOne-pot alkylation-boration of α-haloalkylphosphonatesSynthesis of cyclpentane and pyrrolidine derivatives via regioselective insertion reactionsPhosphorylation leading to P-containing cyclopropanesWadsworth-Emmons reactionsRing expansion of zircnacycles via carbenoid insertion

Synthesis Reference(s)

Tetrahedron Letters, 28, p. 3799, 1987 DOI: 10.1016/S0040-4039(00)96387-1

Check Digit Verification of cas no

The CAS Registry Mumber 3167-63-3 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 3,1,6 and 7 respectively; the second part has 2 digits, 6 and 3 respectively.
Calculate Digit Verification of CAS Registry Number 3167-63:
(6*3)+(5*1)+(4*6)+(3*7)+(2*6)+(1*3)=83
83 % 10 = 3
So 3167-63-3 is a valid CAS Registry Number.
InChI:InChI=1/C5H12ClO3P/c1-3-8-10(7,5-6)9-4-2/h3-5H2,1-2H3

3167-63-3 Well-known Company Product Price

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  • (Code)Product description
  • CAS number
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  • Detail
  • TCI America

  • (D4588)  Diethyl (Chloromethyl)phosphonate  >98.0%(GC)

  • 3167-63-3

  • 1g

  • 850.00CNY

  • Detail
  • TCI America

  • (D4588)  Diethyl (Chloromethyl)phosphonate  >98.0%(GC)

  • 3167-63-3

  • 5g

  • 2,750.00CNY

  • Detail
  • Aldrich

  • (263613)  Diethylchloromethylphosphonate  97%

  • 3167-63-3

  • 263613-1ML

  • 1,104.48CNY

  • Detail

3167-63-3SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 11, 2017

Revision Date: Aug 11, 2017

1.Identification

1.1 GHS Product identifier

Product name 1-[chloromethyl(ethoxy)phosphoryl]oxyethane

1.2 Other means of identification

Product number -
Other names Diethyl chloromethanephosphonate

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:3167-63-3 SDS

3167-63-3Relevant articles and documents

A Convenient Synthesis of Diethyl 1-Chloroalkylphosphonates

Gajda, Tadeusz

, p. 717 - 718 (1990)

The title compounds were obtained in high yield by the reaction of diethyl 1-hydroxyalkylphosphonates with triphenylphosphine carbon tetrachloride.

SYNTHESIS OF INTERMEDIATES USED IN THE MANUFACTURE OF ANTI-HIV AGENTS

-

Page/Page column 25-26, (2016/11/21)

The present invention relates to a process of preparing intermediates of Formula (I). The process comprises of reacting compound of Formula (III) with compound of Formula (V) in the presence of a solvent selected from an alcohol, ether or water to form compound of Formula (I) wherein, R1 is selected from –NH2, Cl, Br, NHCOR", wherein R" is alkyl, aryl, Schiff's base of formula N=CHR', wherein R' is alkyl or aryl; R2 is selected from H, alkyl; R3 and R4, each independently is H; R5 and R6, each independently is H, alkyl; R7 is H, alkyl; and R8 is H, alkyl.

Reactions of α-boranophosphorus compounds with electrophiles: Alkylation, acylation, and other reactions

Antczak, Monika I.,Montchamp, Jean-Luc

supporting information; experimental part, p. 3758 - 3766 (2009/11/30)

(Chemical Equation Presented) The homologation of phosphorus carbenoids with organoboranes leads to α-boranophosphorus compounds, which can be further functionalized through reactions with various electrophiles, either directly or after activation to the

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