92254-97-2Relevant academic research and scientific papers
Synthesis of phosphonamidate peptides by Staudinger reactions of silylated phosphinic acids and esters
Wilkening, Ina,Signore, Giuseppe Del,Hackenberger, Christian P. R.
, p. 349 - 351 (2011/03/17)
The Staudinger reaction of unprotected azido-peptides with silylated phosphinic acids and esters on the solid support offers a straightforward acid-free entry to different phosphonamidate peptide esters or acids under mild conditions in high purity and yield.
N-hydroxylamines: Influence of Substituents on the Competitive Migration of Aryl and Phenyl Groups in the Lossen-like Rearrangement of their O-Methanesulphonyl Derivatives
Harger, Martin J. P.,Smith, Adrian
, p. 1787 - 1792 (2007/10/02)
The N-hydroxylamines ArPhP(O)NHOH (4) (Ar=p-XC6H4; X=MeO, Me, Cl, NO2) have been prepared from the corresponding phosphinic chlorides (3) using O-(trimethylsilyl)hydroxylamine and converted into the O-methanesulphonyl derivatives
