92344-70-2

Upstream product

• 107-93-7 (E)-but-2-enoic acid 
• 106-99-0 buta-1,3-diene 
• 89-94-1 trans-6-methyl-3-cyclohexene-1-carboxaldehyde 
• 92344-80-4 (1S,6S)-6-Methyl-cyclohex-3-enecarboxylic acid 2-((S)-1-phenyl-ethylamino)-ethyl ester 
• 92344-76-8 (1R,6R)-6-Methyl-cyclohex-3-enecarboxylic acid (2-hydroxy-ethyl)-((S)-1-phenyl-ethyl)-amide 
• 92284-47-4 (1R,6R)-6-Methyl-cyclohex-3-enecarboxylic acid ((S)-1-phenyl-ethyl)-amide 
• 92284-36-1 (1S,6S)-6-Methyl-cyclohex-3-enecarbonyl chloride 
• 116996-49-7 <1S-<1α(R^*),6β>>-3-<(6-methyl-3-cyclohexen-1-yl)carbonyl>-4-(phenylmethyl)-2-oxazolidinone 
• 92344-78-0 1S,6S-(-)-6-Methyl-3-cyclohexenyl-methanol 

Downstream Products

• 92284-50-9 3-<(6-Methyl-3-cyclohexenyl)carbonyl>-4-phenyl-2-oxazolidinone 
• 92344-64-4 (1S,2S,5R)-5-Chloro-2-methyl-cyclohexanecarboxylic acid tert-butyl ester 
• 92344-69-9 (1S,2S,4R)-4-Chloro-2-methyl-cyclohexanecarboxylic acid tert-butyl ester 
• 7076-91-7 (+-)-cis-2-methyl-cyclohexanecarboxylic acid 
• 93296-90-3 (+/-)-cis-6-methyl-cyclohex-3-enecarboxylic acid amide 
• 2425-20-9 optically inactive cis-6-methyl-cyclohex-3-enecarboxylic acid sec-butyl ester 
• 2425-23-2 trans-6-methyl-1-ethoxycarbonyl-3-cyclohexene 
• 15111-54-3 methyl trans-6-methyl-3-cyclohexene carboxylate 
• 15177-62-5 trans-2-methylcyclohexanecarboxylic acid 
• 5748-20-9 trimedlure-B1 
• 6070-02-6 trans-o-menthane 
• 99805-92-2 trans-o-4-menthen-8-ol 

Relevant academic research and scientific papers

Enantioselective synthesis of ceralure B1, ethyl cis-5-iodo-trans-2- methylcyclohexane-1-carboxylate

Ethyl (1R, 2R, 5R)-5-iodo-2-methylcyclohexane-1-carboxylate is a potent attractant for the Mediterranean fruit fly. This compound was stereoselectively synthesized on a multigram scale in nine steps in 15% yield. Key steps of the synthesis involved an asymmetric Diels-Alder reaction, iodolactonization, stereoselective reduction of the carbonyl, and inversion of configuration with iodide. (C) 2000 Elsevier Science Ltd.

STUDIES OF COMPOUNDS IN THE MENTHANE SERIES. XIX. SYNTHESIS AND PROPERTIES OF TRANS-o-4-MENTHEN-8-OL AND STEREOISOMERIC o-5-METHEN-8-OLS

Trans-o-4-Menthen-8-ol and cis- and trans-o-5-menthen-8-ols have been prepared via the Diels-Alder reactions of 1,3-butadiene with crotonaldehyde in the presence of boron trifluoride etherate, and piperylene with methyl acrylate, respectively.The dehydration reactions of these alcohols have been studied in the presence of acetic anhydride and potassium bisulfate; the latter reagent demonstrates a high reaction selectivity.

Enantiomers of the Biologically Active Components of the Insect Attractant Trimedlure

The biologically most active components of a synthetic lure that is used to attract male Mediterranean fruit flies are the tert.-butyl esters of cis-4-(and trans-5-)chloro-trans-2-methylcyclohexanecarboxylic acids (1-A and 1-C).These compounds have been s