92372-05-9

Basic information

• Product Name: 1,7,7-trimethylbicyclo[2.2.1]hept-2-yl acetoacetate
• Synonyms: 1,7,7-trimethylbicyclo[2.2.1]hept-2-yl acetoacetate;3-Oxobutanoic acid 1,7,7-trimethylbicyclo[2.2.1]heptan-2-yl ester
• CAS NO: 92372-05-9
• Molecular Formula: C₁₄H₂₂O₃
• Molecular Weight: 238.32268
• EINECS: 296-231-1
• Mol File: 92372-05-9.mol
• Article Data: 4

Chemical Properties

• Boiling Point: 295.4°Cat760mmHg
• Flash Point: 123.9°C
• Appearance: /
• Density: 1.06g/cm³
• Vapor Pressure: 0.00153mmHg at 25°C
• Refractive Index: 1.488
• CAS DataBase Reference: 1,7,7-trimethylbicyclo[2.2.1]hept-2-yl acetoacetate(CAS DataBase Reference)
• NIST Chemistry Reference: 1,7,7-trimethylbicyclo[2.2.1]hept-2-yl acetoacetate(92372-05-9)
• EPA Substance Registry System: 1,7,7-trimethylbicyclo[2.2.1]hept-2-yl acetoacetate(92372-05-9)

Safety Data

• Hazardous Substances Data: 92372-05-9(Hazardous Substances Data)

Usage

Bicyclic structure

Contains a seven-membered ring and a cycloheptane ring

Methyl groups

Three methyl groups are attached to the cycloheptane ring

Functional group

Acetoacetate functional group

Potential applications

May be used as a substrate for various organic reactions

Industrial use

Commonly used as a building block in the synthesis of complex organic molecules

Industries

Pharmaceutical and agrochemical industries

Unique structure

Valuable intermediate in the production of a wide range of organic compounds

InChI:InChI=1/C14H22O3/c1-9(15)7-12(16)17-11-8-10-5-6-14(11,4)13(10,2)3/h10-11H,5-8H2,1-4H3

Upstream product

• 674-82-8 4-methyleneoxetan-2-one 
• 507-70-0 1,7,7-trimethyl bicyclo[2.2.1]heptan-2-ol 
• 141-97-9 ethyl acetoacetate 
• 125-12-2 isobornyl acetate 

Relevant articles and documents

Transesterification of copper(II) β-ketoesterates and acylpyruvates with borneol

Transesterification of copper(II) acetoacetates, copper(II) trifluoroacetoacetate, and copper(II) acylpyruvates with borneol gives the copper(II) chelates of the corresponding bornyl esters in 92-95percent yields.Bornyl acetyl- and perfluoroacylpyruvates were synthesized for the first time by decomposing the respective chelates with hydrogen chloride.Bornyl acylpyruvates react with hydrazine hydrate to give 5-alkyl-3-bornyloxycarbonylpyrazoles.

Asymmetric Aerobic Epoxidation of Unfunctionalized Olefins Catalyzed by Optically Active α-Alkoxycarbonyl-β-ketoiminato Manganese(III) Complexes

Optically active N,N'-ethylenebis(α-alkoxycarbonyl-β-ketoimine) was found to be a new class of effective ligand of manganese(III) complex catalyst for the asymmetric aerobic epoxidation of simple olefins, such as 1,2-dihydronaphthalene derivatives, to afford the corresponding optically active epoxides with good to high enantioselectivities.