924656-46-2

Upstream product

• 127793-62-8 4-((tert-butyldiphenylsilyl)oxy)butanal 
• 2186-92-7 p-Anisaldehyde dimethyl acetal 
• 924656-67-7 4-((2R,3S,6R,7S)-6-Benzyloxy-7-benzyloxymethyl-3-hydroxy-oxepan-2-yl)-butan-2-one 
• 908865-90-7 (2S,3S)-6-(tert-Butyl-diphenyl-silanyloxy)-2-methyl-hexane-1,3-diol 
• 924656-36-0 [(2R,3S,5aR,8R,10aS)-2-(3-Benzyloxy-propyl)-8-(4-methoxy-benzyloxy)-3-methyl-7-methylene-decahydro-1,6-dioxa-heptalen-3-yloxy]-tert-butyl-dimethyl-silane 
• 908865-85-0 Phosphoric acid (2S,3S,4aS,9aR)-2-[3-(tert-butyl-diphenyl-silanyloxy)-propyl]-3,9a-dimethyl-3,4,4a,8,9,9a-hexahydro-2H-1,5-dioxa-benzocyclohepten-6-yl ester diphenyl ester 
• 908866-38-6 (3S,4S)-7-(tert-Butyl-diphenyl-silanyloxy)-4-(4-methoxy-benzyloxy)-3-methyl-heptanal 
• 908865-92-9 (2S,3S)-6-(tert-Butyl-diphenyl-silanyloxy)-3-(4-methoxy-benzyloxy)-2-methyl-hexan-1-ol 
• 924656-30-4 (2R,3S,5S,6S)-6-[3-(tert-Butyl-diphenyl-silanyloxy)-propyl]-2,5-dimethyl-2-vinyl-tetrahydro-pyran-3-ol 
• 908866-41-1 (E)-4-{(2R,3S,5S,6S)-6-[3-(tert-Butyl-diphenyl-silanyloxy)-propyl]-2,5-dimethyl-3-triethylsilanyloxy-tetrahydro-pyran-2-yl}-but-2-enoic acid benzyl ester 
• 924656-45-1 [(2S,3R,5aS,7R,8S,10aR)-7-(3-Benzyloxy-propyl)-8-(tert-butyl-dimethyl-silanyloxy)-3-(4-methoxy-benzyloxy)-8-methyl-decahydro-1,6-dioxa-heptalen-2-yl]-methanol 
• 924657-13-6 3-[(2R,3S,5aR,7S,8R,10aS)-8-Benzyloxy-7-benzyloxymethyl-3-(tert-butyl-dimethyl-silanyloxy)-3-methyl-decahydro-1,6-dioxa-heptalen-2-yl]-propan-1-ol 
• 924656-31-5 (E)-4-{(2R,3S,5S,6S)-6-[3-(tert-Butyl-diphenyl-silanyloxy)-propyl]-3-hydroxy-2,5-dimethyl-tetrahydro-pyran-2-yl}-but-2-enoic acid benzyl ester 
• 924656-42-8 2-[(2R,3S,5aR,7S,8R,10aS)-8-Benzyloxy-7-benzyloxymethyl-3-(tert-butyl-dimethyl-silanyloxy)-3-methyl-decahydro-1,6-dioxa-heptalen-2-yl]-ethanol 

Downstream Products

• 924656-75-7 C₇₃H₁₁₄O₈SeSi₃ 
• 924656-74-6 C₇₀H₁₂₀O₉Si₄ 
• 924656-50-8 C₇₀H₁₁₆O₁₀Si₄ 
• 924656-61-1 C₆₇H₁₀₈O₈Si₃ 
• 924656-60-0 C₆₄H₁₀₆O₉Si₃ 
• 924656-49-5 6-[7-(3-benzyloxy-propyl)-8-(tert-butyl-dimethyl-silanyloxy)-3-(4-methoxy-benzyloxy)-8-methyl-decahydro-1,6-dioxa-heptalen-2-ylmethyl]-2-[3-(tert-butyl-diphenyl-silanyloxy)-propyl]-3,9a-dimethyl-octahydro-1,5-dioxa-benzocycloheptene-7,8-diol 
• 924656-52-0 C₆₆H₁₀₆O₉SSi₃ 
• 924656-54-2 C₆₄H₁₁₂O₉Si₄ 
• 924656-48-4 C₆₆H₉₆O₁₁Si₂ 
• 924656-53-1 C₆₅H₁₀₄O₉Si₃ 
• 924656-51-9 C₆₀H₉₂O₉SSi₂ 
• 924656-70-2 C₅₈H₉₈O₉Si₃ 
• 924656-68-8 6-[7-(3-benzyloxy-propyl)-8-(tert-butyl-dimethyl-silanyloxy)-3-(4-methoxy-benzyloxy)-8-methyl-decahydro-1,6-dioxa-heptalen-2-ylmethyl]-2-[3-(tert-butyl-diphenyl-silanyloxy)-propyl]-3,9a-dimethyl-octahydro-1,5-dioxa-benzocyclohepten-7-ol 

Relevant academic research and scientific papers

Total synthesis, structure revision, and absolute configuration of (-)-brevenal

Total synthesis of structure 1 originally proposed for brevenal, a nontoxic polycyclic ether natural product isolated from the Florida red tide dinoflagellate, Karenia brevis, was accomplished. The key features of the synthesis involved (i) convergent ass