92499-04-2Relevant academic research and scientific papers
Copper-catalyzed intermolecular regioselective hydroamination of styrenes with polymethylhydrosiloxane and hydroxylamines
Miki, Yuya,Hirano, Koji,Satoh, Tetsuya,Miura, Masahiro
supporting information, p. 10830 - 10834 (2013/10/22)
Playing Reversi with H and N: A copper-catalyzed intermolecular regioselective hydroamination of styrenes with polymethylhydrosiloxane and hydroxylamine derivatives has been developed. The catalysis accommodates challenging β-substituted substrates. Moreover, the chiral biphosphine-ligated copper complex successfully forms benzylamines with good enantiomeric ratios. Copyright
One-pot amide synthesis from allyl or benzyl halides and amines by Pd-catalysed carbonylation
Troisi, Luigino,Granito, Catia,Rosato, Francesca,Videtta, Valeria
experimental part, p. 371 - 373 (2010/03/24)
Amides can be prepared from allyl or benzyl halides and primary or secondary amines, using Pd(0) catalyst under CO pressure, in a one-pot synthesis. The reaction proceeds through the acyl palladium halide formation which undergoes an acylic nucleophilic substitution from the amine.
Palladium-tetraphosphine catalysed allylic substitution in water
Feuerstein, Marie,Laurenti, Dorothée,Doucet, Henri,Santelli, Maurice
, p. 2313 - 2315 (2007/10/03)
The cis,cis,cis-1,2,3,4-tetrakis(diphenylphosphinomethyl)cyclopentane/[PdCl (C3H5)]2 system catalyses allylic amination in water with very high substrate/catalyst ratio in good yields. A turnover number of 980 000 can be obtained for the addition of dipropylamine to allyl acetate in the presence of this catalyst.
