926-22-7Relevant academic research and scientific papers
Remote Arylative Substitution of Alkenes Possessing an Acetoxy Group via β-Acetoxy Elimination
Kakiuchi, Fumitoshi,Kochi, Takuya,Kumagai, Takaaki,Muto, Kazuma
supporting information, p. 24500 - 24504 (2021/10/19)
Palladium-catalyzed remote arylative substitution was achieved for the reaction of arylboronic acids with alkenes possessing a distant acetoxy group to provide arylation products having an alkene moiety at the remote position. The use of β-acetoxy elimination as a key step in the catalytic cycle allowed for regioselective formation of unstabilized alkenes after chain walking. This reaction was applicable to various arylboronic acids as well as alkene substrates.
Kinetic Applications of Electron Paramagnetic Resonance Spectroscopy. 38. Rearrangement of β-(Acyloxy)alkyl and β-(benzoyloxy)alkyl Radicals
Barclay, L. R. C.,Griller, D.,Ingold, K. U.
, p. 4399 - 4403 (2007/10/02)
Rate constants for the free-radical rearrangement, RC(O)OCMe2CH2* --> RC(O)OCH2CMe2*, and for the ring-opening reaction, , have been measured by kinetic EPR spectroscopy.In hydrocarbon solvents at 75 deg C with R = methyl and phenyl, the 1,2-acy
