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TIANFU-CHEM trifluoromethanol
Cas No: 1493-11-4
No Data 1 Kilogram 10 Metric Ton/Day Henan Tianfu Chemical Co., Ltd. Contact Supplier
trifluoromethanol
Cas No: 1493-11-4
No Data No Data No Data Shanghai Run-Biotech Co., Ltd. Contact Supplier
Methanol, trifluoro-(6CI,8CI,9CI)
Cas No: 1493-11-4
No Data No Data No Data Antimex Chemical Limied Contact Supplier
trifluoromethanol
Cas No: 1493-11-4
No Data No Data No Data Synova( Tianjin ) Chemical Technology Co,.Ltd Contact Supplier
Methanol, trifluoro-(6CI,8CI,9CI)
Cas No: 1493-11-4
No Data No Data No Data AAA Chem Co.,Limited Contact Supplier

1493-11-4 Usage

InChI:InChI=1/CHF3O/c2-1(3,4)5/h5H

1493-11-4SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 17, 2017

Revision Date: Aug 17, 2017

1.Identification

1.1 GHS Product identifier

Product name Trifluoromethanol

1.2 Other means of identification

Product number -
Other names perfluoro-tert-butyl alcohol

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:1493-11-4 SDS

1493-11-4Synthetic route

trifluoromethyl hypochlorite
22082-78-6

trifluoromethyl hypochlorite

trifluoromethanol
1493-11-4

trifluoromethanol

Conditions
ConditionsYield
With hydrogenchloride; chlorotrifluoromethane
With hydrogenchloride In various solvent(s)
methane
34557-54-5

methane

trifluoroketone
21811-29-0

trifluoroketone

A

methyl radical
2229-07-4

methyl radical

B

trifluoromethanol
1493-11-4

trifluoromethanol

Conditions
ConditionsYield
at 86.9℃; Kinetics; Thermodynamic data; Irradiation; in buffer gas (He);
In various solvent(s) at -38.1℃; under 45.004 Torr; Kinetics; Thermodynamic data; Irradiation; further temperatures; Arrhenius expression, ΔH;
ethane
74-84-0

ethane

trifluoroketone
21811-29-0

trifluoroketone

A

ethyl radical
2025-56-1

ethyl radical

B

trifluoromethanol
1493-11-4

trifluoromethanol

Conditions
ConditionsYield
at 86.9℃; Kinetics; Thermodynamic data; Irradiation; in buffer gas (He);
at 22.9℃; Rate constant;
propane
74-98-6

propane

trifluoroketone
21811-29-0

trifluoroketone

A

n-Propyl-Radikal
2143-61-5

n-Propyl-Radikal

B

trifluoromethanol
1493-11-4

trifluoromethanol

Conditions
ConditionsYield
at 97.9℃; Kinetics; Thermodynamic data; Irradiation; in buffer gas (He);
Isobutane
75-28-5

Isobutane

trifluoroketone
21811-29-0

trifluoroketone

A

t-Butyl radical
1605-73-8

t-Butyl radical

B

trifluoromethanol
1493-11-4

trifluoromethanol

Conditions
ConditionsYield
at 93.9℃; Kinetics; Thermodynamic data; Irradiation; in buffer gas (He);
ethene
74-85-1

ethene

trifluoroketone
21811-29-0

trifluoroketone

A

vinyl radical
2669-89-8

vinyl radical

B

trifluoromethanol
1493-11-4

trifluoromethanol

Conditions
ConditionsYield
at 23.9℃; Mechanism; Rate constant; other alkenes; also eith NO, O2;
Bromotrifluoromethane
75-63-8

Bromotrifluoromethane

A

hypofluorous acid trifluoromethyl ester
373-91-1

hypofluorous acid trifluoromethyl ester

B

Carbonyl fluoride
353-50-4

Carbonyl fluoride

C

carbonyl bromide fluoride
753-56-0

carbonyl bromide fluoride

D

trifluoromethan
75-46-7

trifluoromethan

E

trifluoromethanol
1493-11-4

trifluoromethanol

Conditions
ConditionsYield
With hydrogen; oxygen at 469℃; under 500 Torr; Thermodynamic data; Product distribution; E(act); further reaction times,;
1,1,1,2-tetrafluoroethane
811-97-2

1,1,1,2-tetrafluoroethane

A

Carbonyl fluoride
353-50-4

Carbonyl fluoride

B

formyl fluoride
1493-02-3

formyl fluoride

C

trifluoroacetyl fluoride
354-34-7

trifluoroacetyl fluoride

D

trifluoromethanol
1493-11-4

trifluoromethanol

E

Bis-trifluormethyl-trioxid
1718-18-9

Bis-trifluormethyl-trioxid

Conditions
ConditionsYield
With air; water; chlorine at 22.9℃; under 700 Torr; Product distribution; Irradiation; other partial pressures of the components; reaction without water;
bis(trifluoromethyl)peroxide
927-84-4

bis(trifluoromethyl)peroxide

methyl 3,3,3-trifluoropyruvate
13089-11-7

methyl 3,3,3-trifluoropyruvate

A

trifluoromethanol
1493-11-4

trifluoromethanol

B

2-(trifluoroacetyloxy)-2-methyl-1-propyl radical
88635-50-1

2-(trifluoroacetyloxy)-2-methyl-1-propyl radical

Conditions
ConditionsYield
In 1,1,2-Trichloro-1,2,2-trifluoroethane at -11℃; Product distribution; Irradiation; in EPR cavity; variation of temperature;;
trifluoroketone
21811-29-0

trifluoroketone

A

t-Butyl radical
1605-73-8

t-Butyl radical

B

trifluoromethanol
1493-11-4

trifluoromethanol

Conditions
ConditionsYield
With Isobutane at 23.9℃; Rate constant;
trifluoroketone
21811-29-0

trifluoroketone

trifluoromethanol
1493-11-4

trifluoromethanol

Conditions
ConditionsYield
With methane at -41.8℃; Mechanism; Rate constant; further temperatures;
1,1,1,2-tetrafluoroethane
811-97-2

1,1,1,2-tetrafluoroethane

trifluoroketone
21811-29-0

trifluoroketone

A

trifluoromethanol
1493-11-4

trifluoromethanol

B

1,2,2,2-tetrafluoro-ethyl
40617-75-2

1,2,2,2-tetrafluoro-ethyl

Conditions
ConditionsYield
at 21.9℃; Rate constant;
2,2,2-Trifluoroacetaldehyde
75-90-1

2,2,2-Trifluoroacetaldehyde

trifluoroketone
21811-29-0

trifluoroketone

A

trifluoromethanol
1493-11-4

trifluoromethanol

B

trifluoroacetyl radical
6185-26-8

trifluoroacetyl radical

Conditions
ConditionsYield
Rate constant;
Trifluoro-methanol anion
57178-38-8

Trifluoro-methanol anion

A

Carbonyl fluoride
353-50-4

Carbonyl fluoride

B

trifluoromethanol
1493-11-4

trifluoromethanol

Conditions
ConditionsYield
With nitric acid at 21.9℃; under 0.4 Torr; Rate constant; other reagents;
carbon monoxide
201230-82-2

carbon monoxide

Trifluoromethyl-oxonium

Trifluoromethyl-oxonium

A

oxomethylium
17030-74-9

oxomethylium

B

trifluoromethanol
1493-11-4

trifluoromethanol

Conditions
ConditionsYield
In gas at 24.9℃; Thermodynamic data; ΔH;
1,1,1,2,2-pentafluoroethane
354-33-6

1,1,1,2,2-pentafluoroethane

A

Carbonyl fluoride
353-50-4

Carbonyl fluoride

B

trifluoromethanol
1493-11-4

trifluoromethanol

C

Bis-trifluormethyl-trioxid
1718-18-9

Bis-trifluormethyl-trioxid

D

Perfluormethyl-perfluorethyl-trioxid
17610-65-0

Perfluormethyl-perfluorethyl-trioxid

Conditions
ConditionsYield
With air; chlorine at 21.85℃; under 700 Torr; Kinetics; Further Variations:; Reagents; radical reaction; UV-irradiation;
1-fluoroethane
353-36-6

1-fluoroethane

trifluoroketone
21811-29-0

trifluoroketone

A

trifluoromethanol
1493-11-4

trifluoromethanol

B

C2H4F radicals

C2H4F radicals

Conditions
ConditionsYield
at 22.9℃; Rate constant;
Bromotrifluoromethane
75-63-8

Bromotrifluoromethane

A

Carbonyl fluoride
353-50-4

Carbonyl fluoride

B

trifluoromethanol
1493-11-4

trifluoromethanol

C

CO, CO2

CO, CO2

Conditions
ConditionsYield
With ozone; dinitrogen monoxide at 21.9℃; under 37.5 Torr; for 0.000833333h; Rate constant; Mechanism; Irradiation; further at 14 K, with <18O>O3, var. conc.;
trifluoroketone
21811-29-0

trifluoroketone

A

trifluoromethanol
1493-11-4

trifluoromethanol

B

OH radical

OH radical

Conditions
ConditionsYield
With water at 22.9℃; under 700 Torr; Rate constant;
trifluoroketone
21811-29-0

trifluoroketone

A

trifluoromethanol
1493-11-4

trifluoromethanol

B

OH

OH

Conditions
ConditionsYield
With water at 81.9℃; Rate constant; Mechanism;
trifluoromethylperoxy radical
17167-98-5

trifluoromethylperoxy radical

A

trifluoroketone
21811-29-0

trifluoroketone

B

trifluoromethanol
1493-11-4

trifluoromethanol

C

NO2

NO2

Conditions
ConditionsYield
With nitrogen(II) oxide at 23.9℃; Rate constant; Product distribution; Mechanism; variation of p and NO concentration;
2,2,3,3,3-Pentafluoro-propionaldehyde
422-06-0

2,2,3,3,3-Pentafluoro-propionaldehyde

A

Carbonyl fluoride
353-50-4

Carbonyl fluoride

B

pentafluoropropionic acid
422-64-0

pentafluoropropionic acid

C

trifluoromethanol
1493-11-4

trifluoromethanol

Conditions
ConditionsYield
With hydrogen; oxygen; chlorine at 22.85℃; Product distribution; Further Variations:; Pressures; var. concentration ratio H2:C2F5CHO; UV-irradiation;
Carbonyl fluoride
353-50-4

Carbonyl fluoride

trifluoromethanol
1493-11-4

trifluoromethanol

Conditions
ConditionsYield
With hydrogen fluoride at -196 - 0℃;
With hydrogen fluoride at -196 - 20℃; Autoclave; Sealed tube;
4,6-dibromobenzo[c][1,2,5]oxadiazole
769-56-2

4,6-dibromobenzo[c][1,2,5]oxadiazole

3-Formylphenylboronic acid
87199-16-4

3-Formylphenylboronic acid

ethyl pyrrolidine-2-carboxylate hydro chloride

ethyl pyrrolidine-2-carboxylate hydro chloride

trifluoromethanol
1493-11-4

trifluoromethanol

Conditions
ConditionsYield
With dmap; sodium tetrahydroborate; tetrabutyl ammonium fluoride; sodium carbonate; triethylamine; aniline
3-ethyl-3-(hydroxymethyl)oxetane
3047-32-3

3-ethyl-3-(hydroxymethyl)oxetane

trifluoromethanol
1493-11-4

trifluoromethanol

1,3-dimethylperfluorobenzene
80979-93-7

1,3-dimethylperfluorobenzene

C15H17F5O3

C15H17F5O3

Conditions
ConditionsYield
Stage #1: 3-ethyl-3-(hydroxymethyl)oxetane; 2,4,5,6-tetrafluoro-m-xylene With potassium hydride In tetrahydrofuran at 20℃; for 22h; Inert atmosphere; Cooling with ice;
Stage #2: trifluoromethanol With potassium hydride In tetrahydrofuran at 20℃; for 20h;
86%
Cyclopentanecarboxylic acid chloride
4524-93-0

Cyclopentanecarboxylic acid chloride

trifluoromethanol
1493-11-4

trifluoromethanol

2-methyl-5,6,7-trihydropyrido[2,3-d]pyrimidine

2-methyl-5,6,7-trihydropyrido[2,3-d]pyrimidine

4-chloro-7-fluoro-6-nitroquinazoline
162012-70-6

4-chloro-7-fluoro-6-nitroquinazoline

C23H23F3N6O2

C23H23F3N6O2

Conditions
ConditionsYield
Stage #1: trifluoromethanol; 2-methyl-5,6,7-trihydropyrido[2,3-d]pyrimidine; 4-chloro-7-fluoro-6-nitroquinazoline
Stage #2: With iron(III) chloride; hydrazine hydrate; pyrographite
Stage #3: Cyclopentanecarboxylic acid chloride
48.7%
trifluoromethanol
1493-11-4

trifluoromethanol

1-Norbornyl triflate
29488-82-2

1-Norbornyl triflate

A

1-norbornyl alcohol
51566-98-4

1-norbornyl alcohol

B

1-Trifluoromethoxy-bicyclo[2.2.1]heptane

1-Trifluoromethoxy-bicyclo[2.2.1]heptane

Conditions
ConditionsYield
With 2,6-dimethylpyridine; water at 70℃; Kinetics;A 14 % Chromat.
B 86 % Chromat.
trifluoromethanol
1493-11-4

trifluoromethanol

Trifluoro-methanesulfonic acid 4-methyl-bicyclo[2.2.1]hept-1-yl ester

Trifluoro-methanesulfonic acid 4-methyl-bicyclo[2.2.1]hept-1-yl ester

A

4-Methyl-bicyclo[2.2.1]heptan-1-ol

4-Methyl-bicyclo[2.2.1]heptan-1-ol

B

1-Methyl-4-trifluoromethoxy-bicyclo[2.2.1]heptane

1-Methyl-4-trifluoromethoxy-bicyclo[2.2.1]heptane

Conditions
ConditionsYield
With 2,6-dimethylpyridine; water at 80℃; Rate constant;A 15 % Chromat.
B 85 % Chromat.
trifluoromethanol
1493-11-4

trifluoromethanol

Trifluoro-methanesulfonic acid 4-trimethylsilanyl-bicyclo[2.2.1]hept-1-yl ester
183729-65-9

Trifluoro-methanesulfonic acid 4-trimethylsilanyl-bicyclo[2.2.1]hept-1-yl ester

A

4-Trimethylsilanyl-bicyclo[2.2.1]heptan-1-ol
183729-69-3

4-Trimethylsilanyl-bicyclo[2.2.1]heptan-1-ol

B

Trimethyl-(4-trifluoromethoxy-bicyclo[2.2.1]hept-1-yl)-silane

Trimethyl-(4-trifluoromethoxy-bicyclo[2.2.1]hept-1-yl)-silane

Conditions
ConditionsYield
With 2,6-dimethylpyridine; water at 55℃; Kinetics;A 18 % Chromat.
B 82 % Chromat.
trifluoromethanol
1493-11-4

trifluoromethanol

A

Carbonyl fluoride
353-50-4

Carbonyl fluoride

B

HF

HF

Conditions
ConditionsYield
at 22.9℃; Rate constant;
In various solvent(s) at 298℃; for 0.833333h; Rate constant;
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