927434-10-4Relevant academic research and scientific papers
A Metal-Free Synthesis of 2-Alkyl(or Aryl) Thiomethyl-2-cyclohexenones from Cyclic Morita–Baylis–Hillman Bromides
Baioui, Narjes,Abidi, Ahlem,Rezgui, Farhat
, p. 704 - 709 (2016/09/20)
Under mild conditions, an efficient and rapid S-allylation of thiols with cyclic Morita–Baylis–Hillman (MBH) bromides without the need of a transition-metal catalyst or an expensive additive is described herein. Treatment of the MBH bromides with various
Transition-metal-free nucleophilic allylic substitutions of Morita–Baylis–Hillman bromides with aliphatic and aromatic amines
Baioui, Narjes,Elleuch, Haitham,Rezgui, Farhat
, p. 1796 - 1802 (2016/11/18)
A simple protocol for the preparation of functionalized allylic amines under mild, transition-metal-free conditions from the reaction of Morita–Baylis–Hillman (MBH) bromides with amines is described herein. The treatment of the MBH bromides with various amines in the presence of NaI and Et3N in aqueous acetone solution and at room temperature affords the corresponding functionalized allyl amines in moderate to good yields (45–87%). The reaction is rapid and carried out at room temperature.
The intramolecular reductive cyclization of cyclic enones
Handy, Scott T.,Omune, Duncan
, p. 1366 - 1371 (2007/10/03)
The reductive cyclization (electrohydrocyclization reaction) of tethered cyclic enones has been investigated under electrochemical, metal-mediated, and photochemical conditions. The tricyclic products are generally formed with excellent stereoselectivity,
