934339-35-2

Basic information

• Product Name: 3-O-benzoyl-6-deoxy-6-diethylphosphono-1,2-O-isopropylidene-D-allofuranose
• Synonyms: 3-O-benzoyl-6-deoxy-6-diethylphosphono-1,2-O-isopropylidene-D-allofuranose
• CAS NO: 934339-35-2
• Molecular Weight: 444.419
• Mol File: 934339-35-2.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: 3-O-benzoyl-6-deoxy-6-diethylphosphono-1,2-O-isopropylidene-D-allofuranose(CAS DataBase Reference)
• NIST Chemistry Reference: 3-O-benzoyl-6-deoxy-6-diethylphosphono-1,2-O-isopropylidene-D-allofuranose(934339-35-2)
• EPA Substance Registry System: 3-O-benzoyl-6-deoxy-6-diethylphosphono-1,2-O-isopropylidene-D-allofuranose(934339-35-2)

Safety Data

• Hazardous Substances Data: 934339-35-2(Hazardous Substances Data)

Upstream product

• 762-04-9 phosphonic acid diethyl ester 
• 98-88-4 benzoyl chloride 
• 582-52-5 1,2:5,6-di-O-isopropylidene-α-D-glucofuranose 
• 29474-73-5 (+)-3-deoxy-1,2:5,6-di-O-isopropylidene-α-D-allofuranos-3-yl benzoate 
• 2847-00-9 1,2:5,6-di-O-isopropylidene-α-D-hexofuran-3-ulose 
• 143504-31-8 3-O-Benzoyl-6-deoxy-6-iodo-1,2-O-isopropylidene-α-D-allofuranose 
• 122-52-1 triethyl phosphite 
• 2595-05-3 Diacetone D-glucose 
• 159043-21-7 3-O-Benzoyl-1,2-O-isopropyliden-6-O-(p-tolylsulfonyl)-α-D-allofuranose 

Relevant articles and documents

Improvement of the synthesis of sugar phosphonates using microwave irradiations

Sugar and nucleoside phosphonates have been prepared using a microwave-assisted reaction. Results concerning optimization of the reaction for various substrates as well as comparison of thermal and microwave experimental conditions of the Michaelis-Arbuzov reaction is reported. Copyright Taylor & Francis Group, LLC.

Ex-chiral-pool synthesis of β-hydroxyphosphonate nucleoside analogues

A new series of mononucleotide analogues bearing a nonhydrolysable P-C bond instead of the P-O phosphate linkage is presented. We intend to set up an approach that allows the synthesis of β-hydroxyphosphonate nucleoside analogues as a single diastereoisomer. In this respect, the key "sugar-phosphonate" intermediate was obtained through an Arbusov reaction from an iodosugar derivative in which the stereochemistry of the β-hydroxy group is determined by the choice of the starting material and remains in the resulting nucleotide analogues. Wiley-VCH Verlag GmbH & Co. KGaA, 2007.