94137-50-5Relevant academic research and scientific papers
Hypervalent Iodine Oxidation of Flavanone. Synthesis of cis- and trans-3-Hydroxyflavanones
Moriarty, Robert M.,Prakash, Om
, p. 151 - 153 (1985)
The synthesis of cis-3-hydroxyflavanone (3a) from flavanone (1) via acid-catalyzed hydrolysis of dimethyl acetal 4 formed by C6H5I(OAc)2-KOH/CH3OH oxidation is described.Unger more vigrous hydrolytic conditions isomerization accompanies hydrolysis of 4 wi
Hypervalent Iodine Oxidation of α,β-Unsaturated Ketones: Chromone, Flavone, Chalcone, and Flavanone
Moriarty, Robert M.,Prakash, Om,Freeman, Wade A.
, p. 927 - 929 (2007/10/02)
Reaction of the title compounds with PhI(OAc)2 and MeOH-KOH leads to α-hydroxydimethylacetal β-methoxy products regiospecifically and stereospecifically, as demonstrated by X-ray diffraction.
