Hypervalent Iodine Oxidation of Flavanone. Synthesis of cis- and trans-3-Hydroxyflavanones

DOI: 10.1021/jo00202a001

Source and publish data:

Journal of Organic Chemistry p. 151 - 153 (1985)

Update date:2022-08-04

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Authors:

Moriarty, Robert M.

Prakash, Om

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Article abstract of DOI:10.1021/jo00202a001

The synthesis of cis-3-hydroxyflavanone (3a) from flavanone (1) via acid-catalyzed hydrolysis of dimethyl acetal 4 formed by C6H5I(OAc)2-KOH/CH3OH oxidation is described.Unger more vigrous hydrolytic conditions isomerization accompanies hydrolysis of 4 wi

Full text of DOI:10.1021/jo00202a001

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