93292-64-9

Upstream product

• 58479-61-1 tert-butylchlorodiphenylsilane 
• 93292-41-2 2-deoxy-3-O-(tert-butyldiphenylsilyl)-4,5-O-isopropylidene-D-erythro-pentose diethyl dithioacetal 
• 93292-42-3 2-deoxy-3-O-(tert-butyldiphenylsilyl)-4,5-bis-O-(1-methylethylidene)-D-erythro-pentose 
• 93292-62-7 (2R,3S)-3-(tert-Butyl-diphenyl-silanyloxy)-octane-1,2-diol 
• 93292-61-6 tert-Butyl-[(S)-1-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-hexyloxy]-diphenyl-silane 
• 93292-63-8 (S)-2-(tert-butyldiphenylsilyloxy)heptanal 
• 118908-15-9 (E)-(S)-4-(tert-Butyl-diphenyl-silanyloxy)-non-2-enal 
• 133988-97-3 ethyl (4S)-(2E)-4-tert-butyldiphenylsilyloxy-2-nonenoate 

Downstream Products

• 94292-89-4 4-{(4S,5R)-5-[(1E,3E,5E,7E)-(S)-9-(tert-Butyl-diphenyl-silanyloxy)-tetradeca-1,3,5,7-tetraenyl]-2-oxo-[1,3]dioxolan-4-yl}-butyric acid ethyl ester 
• 94235-56-0 (5S,6R,15S)-(7E,9E,11Z,13E)-15-O-tert-butyldiphenylsilyl-5,6-O-carbonyllipoxin A₄ ethyl ester 
• 93292-66-1 <(4S)-(2E)-4-tert-butyldiphenylsilyloxy-2-nonen-yl>triphenylphosphonium bromide 
• 93292-65-0 1-bromo-(4S),(2E)-4-tert-butyldiphenylsilyloxy-2-nonene 

Relevant academic research and scientific papers

Lipoxins A4 and B4. Total Synthesis Including Deprotection Studies

The total synthesis of lipoxins A4 and B4 (LXA4 and LXB4) as well as of their all-trans isomers is reported.A study concerning the final steps of deprotection of silyl ether, cyclic carbonate and ethyl ester assisted by a high-speed scanning UV spectropho

TOTAL SYNTHESIS OF LIPOXINS A4 AND B4 FROM D-ISOASCORBIC ACID

A total convergent synthesis of lipoxins A4 and B4 has been carried out via four optically pure α-hydroxy and α,β-dihydroxyaldehydes, obtained from D-isoascorbic acid as a single starting material.Connection by a six carbons unit uses Wittig-type reaction