94532-27-1Relevant articles and documents
DISCOVERY AND X-RAY CRYSTAL STRUCTURE OF A NEW HOST COMPOUND: 1,3,4-TRIS(PHENYLTHIO)BENZOTHIENOPYRIDINE
Gilmore, Christopher J.,MacNicol, David D,Murphy, Anthony,Russel, Marie A.
, p. 4303 - 4306 (1984)
In 1,3-dimethyl-2-imidazolidinone (DMEU) as solvent, pentafluoropyridine reacts with PhSNa to give an essentially quantitative yield of pentakis(phenylthio)pyridine (1); however, analogous reaction with pentachloropyridine leads to the unexpected co-formation of the title compound (2), a new host whose crystal structure has been elucidated by X-ray methods for both the unsolvated crystal and for the chlorobenzene inclusion compound.