94540-42-8

Basic information

• Product Name: (±)-2-methyl-2-phenyl-3,4-dihydronaphthalin-1(2H)-one
• Synonyms: (±)-2-methyl-2-phenyl-3,4-dihydronaphthalin-1(2H)-one
• CAS NO: 94540-42-8
• Molecular Weight: 236.313
• Mol File: 94540-42-8.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: (±)-2-methyl-2-phenyl-3,4-dihydronaphthalin-1(2H)-one(CAS DataBase Reference)
• NIST Chemistry Reference: (±)-2-methyl-2-phenyl-3,4-dihydronaphthalin-1(2H)-one(94540-42-8)
• EPA Substance Registry System: (±)-2-methyl-2-phenyl-3,4-dihydronaphthalin-1(2H)-one(94540-42-8)

Safety Data

• Hazardous Substances Data: 94540-42-8(Hazardous Substances Data)

Upstream product

• 98-83-9 isopropenylbenzene 
• 1119036-78-0 2-(3-phenylbut-3-en-1-yl)benzaldehyde 
• 3360-54-1 3-bromo-2-phenylprop-1-ene 
• 1590-08-5 2-methyl-1-tetralone 
• 3972-65-4 1-bromo-4-tert-butylbenzene 
• 108-86-1 bromobenzene 
• 7498-87-5 2-phenyl-3,4-dihydro-2H-naphthalen-1-one 
• 74-88-4 methyl iodide 
• 108-90-7 chlorobenzene 
• 591-50-4 iodobenzene 

Downstream Products

• 408319-01-7 2-Methyl-2-phenyl-tetralol-⁽¹⁾ 
• 104049-32-3 n-butyl-6 methyl-2 phenyl-2 tetralone-1 
• 29304-63-0 2-methyl-1-phenylnaphthalene 
• 25634-92-8 2-methyl-1-phenyl-3,4-dihydronaphthalene 

Relevant articles and documents

Asymmetric arylation of ketone enolates

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Enantioselective α-arylation of cyclic ketones catalyzed by a combination of an unmodified Cinchona alkaloid and a palladium complex

A palladium/Cinchona alkaloid-catalyzed α-arylation between cyclic ketones and aryl halides under phosphine-free conditions is presented. The use of a simple, unmodified Cinchona alkaloid results in high levels of activity and selectivity with up to 93% ee. These enantioinduction levels are comparable or even higher than the ones reported using palladium/BINAP complexes. To the best of our knowledge, this represents the first use of unmodified Cinchona alkaloids as ligands/catalysts in asymmetric transition metal complex-catalyzed cross-coupling reactions. Copyright

Synthesis and reactivity of chiral pentavalent bismuth derivatives

Eight new pentavalent organobismuth derivatives were synthesized by the reactions of triphenylbismuth or phenyl-2,2"-biphenylenebismuth with chiral (1R)-(-)-camphor-10-sulfonic, (-)-menthyloxyacetic, or (R)-3-phenylbutyric acids. Enantioselective C-arylat