94550-18-2

Basic information

• Product Name: dimethyl meso-2,3-dibenzoylsuccinate
• CAS NO: 94550-18-2
• Molecular Weight: 354.359
• Mol File: 94550-18-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: dimethyl meso-2,3-dibenzoylsuccinate(CAS DataBase Reference)
• NIST Chemistry Reference: dimethyl meso-2,3-dibenzoylsuccinate(94550-18-2)
• EPA Substance Registry System: dimethyl meso-2,3-dibenzoylsuccinate(94550-18-2)

Safety Data

• Hazardous Substances Data: 94550-18-2(Hazardous Substances Data)

Upstream product

• 614-27-7 methyl 3-oxo-3-phenylpropionate 
• 1807-69-8 2-diazo-3-oxo-3-phenyl-propionic acid methyl ester 
• 802-60-8 trans-1-cyclohexyl-2,3-dibenzoylaziridine 
• 762-42-5 dimethyl acetylenedicarboxylate 
• 802-60-8 cis-1-cyclohexyl-2,3-dibenzoylaziridine 
• 101871-93-6 2-hydrazono-3-oxo-3-phenyl-propionic acid methyl ester 
• 18725-21-8 3,6-diphenyl-cyclohexa-3,5-diene-1r,2c-dicarboxylic acid dimethyl ester 

Downstream Products

• 19799-49-6 2,5-diphenyl-furan-3,4-dicarboxylic acid 
• 84269-36-3 Dimethyl 2,5-diphenylfuran-3,4-dicarboxylate 

Relevant articles and documents

Phototransformations of C-benzoylaziridines. Dipolarophilic trapping of photogenerated azomethine ylides

The phototransformations of a few 2,3-diaroylaziridines and 2-aryl-3-aroylaziridines have been studied by steady-state photolysis and product analysis.The formation of various photoproducts could be substantiated by ring opening via C-C bond cleavage (leading to azomethine ylides), intramolecular hydrogen abstraction, and C-N bond cleavage.Isolation of stereospecific 3-pyrrolidine derivatives from the photoreaction of benzoylaziridines in the presence of DMAD confirms our previous results concerning the azomethine ylides as major transient intermediates, produced under laser pulse photoexcitation.Dimethyl 1-cyclohexyl-2-benzoylpyrrole-3,4-dicarboxylate (25), one of the photoadducts derived from the reaction of 1a and 1b with DMAD undergoes a novel and unusual photoarrangement to give dimethyl 2-(1-benzoylcyclohexyl)pyrrole-3,4-dicarboxylate (27), the structure of which was confirmed through X-ray crystallographic analysis.