94612-47-2

Basic information

• Product Name: Benzenamine, 4-bromo-N-[(4-methylphenyl)methylene]-, (Z)-
• CAS NO: 94612-47-2
• Molecular Formula: C14H12BrN
• Molecular Weight: 274.16
• Mol File: 94612-47-2.mol
• Article Data: 19

Chemical Properties

• CAS DataBase Reference: Benzenamine, 4-bromo-N-[(4-methylphenyl)methylene]-, (Z)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenamine, 4-bromo-N-[(4-methylphenyl)methylene]-, (Z)-(94612-47-2)
• EPA Substance Registry System: Benzenamine, 4-bromo-N-[(4-methylphenyl)methylene]-, (Z)-(94612-47-2)

Safety Data

• Hazardous Substances Data: 94612-47-2(Hazardous Substances Data)

Upstream product

• 104-87-0 4-methyl-benzaldehyde 
• 106-40-1 4-bromo-aniline 
• 589-18-4 4-Methylbenzyl alcohol 
• 586-78-7 para-nitrophenyl bromide 

Downstream Products

• 94612-25-6 13g 
• 94612-32-5 1-(4-Bromo-phenyl)-3-chloro-3-phenylsulfanyl-4-p-tolyl-azetidin-2-one 
• 121766-24-3 1-(4-Bromo-phenyl)-4-p-tolyl-azetidine-2,3-dione 
• 94612-25-6 1-(4-Bromo-phenyl)-3-phenylsulfanyl-4-p-tolyl-azetidin-2-one 
• 15818-64-1 N-(4-methylbenzyl)aniline 
• 1451070-79-3 1,4-bis(4-bromophenyl)-2,5-bis(4-methylphenyl)-1,4-dihydropyrrolo[3,2-b]pyrrole 

Relevant articles and documents

Au(I) Catalyzed Synthesis of Densely Substituted Pyrazolines and Dihydropyridines via Sequential Aza-Enyne Metathesis/6π-Electrocyclization

A gold(I) autotandem catalysis protocol is reported for the de novo synthesis of densely substituted pyrazolines and dihydropyridines from the corresponding imine derivatives in a highly regioselective fashion via a one-pot aza-enyne metathesis/6π-electrocyclization sequence. The substituents on the nitrogen atom of the imine perfectly control the reaction pathways from the pivotal 1-azabutadiene intermediate; thus, carbazates were converted into pyrazolines via 6π-electrocyclization of α,β-unsaturated hydrazones, while aryl imines provided dihydropyridines via 6π-electrocyclization of 3-azahexatrienes.

Synthesis and characterization of tetrachloro-1,3-oxazepine derivatives and evaluation of their biological activities

6,7,8,9-Tetrachloro[1,3]oxazepine-1,5-dione derivatives 1b-10b have been synthesized by reacting Schiff bases 1a-10a with tetrachlorophthalic anhydride (TCPA) under (2 + 5 → 7) cycloaddition reaction conditons. All reactions had been monitored using TLC.

C-N Bond Formation Catalyzed by Ruthenium Nanoparticles Supported on N-Doped Carbon via Acceptorless Dehydrogenation to Secondary Amines, Imines, Benzimidazoles and Quinoxalines

Ruthenium nanoparticles (NPs) supported on N-doped carbon (Ru/N?C) were prepared by the pyrolysis of cis-Ru(phen)2Cl2 loaded onto carbon powder (VULCAN XC72R) at 800 °C. Ru/N?C NPs (0.2 mol% Ru) selectively catalyzed either acceptorless dehydrogenation coupling (ADC) or auto-transfer-hydrogen (ATH) reactions of amines with alcohols to imines and secondary amines. Such selectivity could be controlled by the choice of alkali metal ion associated with the base. Under similar catalytic conditions, the ADC cross-coupling of diamines with primary alcohols or diols afforded the corresponding benzimidazoles and quinoxalines in good to excellent yields. This catalytic system displayed good activity, recyclability, and wide applicability to a diverse range of substrates.