946512-97-6

Upstream product

• 55628-54-1 3,4,6-tri-O-benzyl-D-glucal 
• 108-59-8 malonic acid dimethyl ester 
• 67-56-1 methanol 
• 1334529-20-2 C₃₁H₃₂O₈ 

Downstream Products

• 946512-99-8 methyl 3,4,6-tri-O-benzyl-2-deoxy-2-C-[(methoxycarbonyl)methyl]-β-D-glucopyranoside 
• 1032716-06-5 methyl 3,4,6-tri-O-benzyl-2-deoxy-2-C-[(dicarboxy)methyl]-β-D-glucopyranoside 
• 1032716-09-8 methyl 3,4,6-tri-O-benzyl-2-deoxy-2-C-[bis-(hydroxymethyl)methyl]-β-D-glucopyranoside 
• 1203550-47-3 methyl 3,4,6-tri-O-benzyl-2-deoxy-2-C-[1,1-bis-(methoxycarbonyl)-ethyl]-β-D-glucopyranoside 
• 1334529-24-6 C₃₇H₄₂O₉ 
• 1334529-25-7 C₃₇H₃₈O₉ 
• 1334529-20-2 C₃₁H₃₂O₈ 
• 1334529-26-8 C₄₅H₄₆O₉ 
• 1124226-20-5 (8aR,9R,10S,11R,12aS,Z)-9,10-bis(benzyloxy)-11-(benzyloxymethyl)-8a,9,10,11-tetrahydro-2H-pyrano[2,3-b][1,6]dioxecin-7(5H,8H,12aH)one 
• 1295578-49-2 octadecyl 3,4,6-tri-O-benzyl-2-deoxy-2-[(octadecyloxycarbonyl)methyl]-α-D-glucopyranoside 
• 1295578-48-1 dodecyl 3,4,6-tri-O-benzyl-2-deoxy-2-[(dodecyloxycarbonyl)methyl]-α-D-glucopyranoside 
• 1295578-47-0 cyclohexyl 3,4,6-tri-O-benzyl-2-deoxy-2-[(cyclohexyloxycarbonyl)methyl]-α-D-glucopyranoside 
• 1295578-44-7 ethyl 3,4,6-tri-O-benzyl-2-deoxy-2-[(ethoxycarbonyl)methyl]-β-D-glucopyranoside 
• 1295578-45-8 ethyl 3,4,6-tri-O-benzyl-2-deoxy-2-[(ethoxycarbonyl)methyl]-α-D-glucopyranoside 

Relevant academic research and scientific papers

Lewis acid-catalyzed stereoselective lactonization and subsequent glycosidation of 2-C-malonyl carbohydrates

Gold(iii) bromide is a suitable catalyst for the stereoselective cyclization of 2-C-malonyl carbohydrates to the anomeric center under retention of one ester group. Reopening of the lactones with alcohols in the presence of TMSOTf affords allyl, propargyl

Convenient syntheses and transformations of 2-C-malonyl carbohydrates

2-C-malonyl carbohydrates were synthesized in only few steps and high yields by radical additions of malonates to glycals. For the first time, the undesired formation of nitrates was completely suppressed with anhydrous cerium ammonium nitrate (CAN) as ox

Simple synthesis of 2-C-branched glyco-acetic acids

Only three steps are required for the selective synthesis of 2-C-branched glyco-acetic acids from glycals by radical addition and decarboxylation. The Royal Society of Chemistry.