95102-89-9

Basic information

• Product Name: 2-Butenoic acid, 2-methyl-3-phenyl-, ethyl ester
• CAS NO: 95102-89-9
• Molecular Formula: C13H16O2
• Molecular Weight: 204.269
• Mol File: 95102-89-9.mol
• Article Data: 19

Chemical Properties

• CAS DataBase Reference: 2-Butenoic acid, 2-methyl-3-phenyl-, ethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Butenoic acid, 2-methyl-3-phenyl-, ethyl ester(95102-89-9)
• EPA Substance Registry System: 2-Butenoic acid, 2-methyl-3-phenyl-, ethyl ester(95102-89-9)

Safety Data

• Hazardous Substances Data: 95102-89-9(Hazardous Substances Data)

Upstream product

• 98-86-2 acetophenone 
• 535-11-5 Ethyl 2-bromopropionate 
• 40309-46-4 3-hydroxy-2-methyl-3-phenylbutyric acid ethyl ester 
• 5466-29-5 ethyl 2,3-epoxy-2-methyl-3-phenylbutanoate 
• 98-80-6 phenylboronic acid 
• 64-17-5 ethanol 
• 75-03-6 ethyl iodide 
• 21382-82-1 (carbethoxyethylidene)triphenylphosphorane 
• 108-86-1 bromobenzene 
• 1029612-58-5 (E)-ethyl 3-(p-toluenesulfonyloxy)-2-methylbut-2-enoate 
• 1029612-60-9 (Z)-ethyl 3-(p-toluenesulfonyloxy)-2-methylbut-2-enoate 
• 198277-79-1 (α-ethoxycarbonylvinyl)diisobutylaluminium 
• 623-47-2 propynoic acid ethyl ester 
• 609-14-3 2-acetylpropanoic acid ethyl ester 

Downstream Products

• 91142-53-9 2-methyl-3-phenyl-crotonic acid 
• 802294-64-0 propionic acid 
• 98-86-2 acetophenone 
• 68668-75-7 (E)-2-methyl-3-phenylbut-2-enoyl chloride 
• 1206614-85-8 (2E)-2-methyl-3-phenylbut-2-enal 
• 1404439-20-8 N-(2,3-dimethyl-1H-inden-1-yl)-4-methylbenzenesulfonamide 
• 26905-45-3 C₁₁H₁₄O 
• 109640-15-5 ethyl 2-methyl-3-phenylbutanoate 
• 91142-22-2 2-methyl-3-phenylbut-2-enal 

Relevant articles and documents

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An Epoxide-Mediated Deprotection Method for Acidic Amide Auxiliary

A practical method for the removal of a versatile acidic amide auxiliary has been developed. Facile alcoholysis of the amide in the presence of KOAc is enabled by an epoxide, which mechanistically resembles the removal of the Myers' auxiliary. The protocol has been applied to the removal of a variety of amide substrates and their C-H functionalization products with high efficiency and low cost, representing a step forward toward the development of a versatile directing group for C-H activation.