α-HALOALKANESULFONYL BROMIDES IN ORGANIC SYNTHESIS. 4. REGIOSELECTIVE γ-DEPROTONATION OF α,β-UNSATURATED SULFONES. A SIMPLE SYNTHESIS OF 2-ALKYL-1,3-BUITADIENES

DOI: 10.1016/S0040-4039(01)81601-4

Source and publish data:

Tetrahedron Letters p. 5469 - 5472 (1984)

Update date:2022-09-26

Topics:

Authors:

Block, Eric

Eswarakrishnan, Venkatachalam

Gebreyes, Kassu

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(01)81601-4

A simple method for converting 2-methyl-1-alkenes into 2-alkyl-1,3-butadienes is described.Evidence for complexation of lithium cations by sulfonyl groups in the course of reactions of α,β-unsaturated sulfones with LiOt-Bu is presented.

Full text of DOI:10.1016/S0040-4039(01)81601-4

Products guided by the article

Product name:Cyclohexene, 1-ethenyl-3-methyl-

Cas No:95205-65-5

R&D Labs maybe for 95205-65-5

Daqing New Century Fine Chemical Co., Ltd.(expird)

Contact:010-57126694

Address:No.39, jinxing cun, honggang district
MENGNA

Contact:18698110882

Address:1303 No2 building,LuoMa Garden,YongAn Road,Hexi District,Tianjin city
Hangzhou Mole's Science & Technology Co.,Ltd.(expird)

Contact:+86-571-56880228

Address:15F Guodu development Building, NO.182 Zhaohui Road
LIANYUNGANG YC FINE CHEMICAL CO., LTD

Contact:+86-518-858 99188

Address:Shangdong Modern Bldg, South Greenpark Road, Lianyungang, Jiangsu Pro. China
Shanghai Hanhong Scientific Co.,Ltd.

website:http://www.chemvia.com

Contact:+86-21-64541543,54280654,13918533501

Address:Jiachuan Road 245

Relevant to this article

Synthesis and structural characterization of hexacoordinate silicon, germanium, and titanium complexes of the E. coli siderophore enterobactin

Doi:10.1002/chem.201301825
(2013)
Synthesis of soluble oligo- and polymeric pentacene-based materials

Doi:10.1016/j.tet.2008.09.041
(2008)
Synthesis of bridged piperazines with σ receptor affinity

Doi:10.1016/j.ejmech.2007.02.005
(2007)
A general approach to 3-n-butyl-5-alkylindolizidines: Total synthesis of (-)-indolizidine 195B

Doi:10.1021/jo7015423
(2007)
Iron, ruthenium, and osmium complexes supported by the bis(silyl) chelate ligand (9,9-dimethylxanthene-4,5-diyl)bis(dimethylsilyl): Synthesis, characterization, and reactivity

Doi:10.1021/om700720s
(2007)
Novel fluorinated derivatives of the broad-spectrum MMP inhibitors N-hydroxy-2(R)-[[(4-methoxyphenyl)sulfonyl](benzyl)- and (3-picolyl)-amino]-3- methyl-butanamide as potential tools for the molecular imaging of activated MMPs with PET

Doi:10.1021/jm0708533
(2007)

Article Doi