95316-36-2Relevant academic research and scientific papers
Formation of cyclopropanes by homolytic substitution reactions of 3- iodopropyl radicals: Preparative and rate studies
Curran, Dennis P.,Gabarda, Ana E.
, p. 3327 - 3336 (2007/10/03)
Reduction of 2-substituted 1,3-diiodopropane derivatives with tin hydride provides substituted cyclopropanes. The reaction occurs through a homolytic substitution of the 3-iodopropyl radical, which has a rate constant of about 5 x 105 s-1 at 80°C.
Synthesis of Helical Molecules Based on 5,6,6a,7,8,12b-Hexahydrobenzophenanthrene-5,8-dione
Cheung, Julie,Field, Leslie D.,Regaglia, Francesca,Sternhell, Sever
, p. 1707 - 1726 (2007/10/03)
Synthetic routes based on Newman'synthesis of a number of polycyclic aromatic hydrocarbons were modified and developed to give a convenient preparation (Scheme 1) of 11 helical molecules formally based on hexalindione (1).In contrast to Newman's work, we
