954-46-1

Basic information

• Product Name: 9-NITROPHENANTHRENE
• Synonyms: 9-NITROPHENANTHRENE;9-nitro-phenanthren;Phenanthrene, 9-nitro-
• CAS NO: 954-46-1
• Molecular Formula: C₁₄H₉NO₂
• Molecular Weight: 223.23
• Mol File: 954-46-1.mol
• Article Data: 5

Chemical Properties

• Melting Point: 116-117 °C
• Boiling Point: 413.3°Cat760mmHg
• Flash Point: 207.5°C
• Appearance: /
• Density: 1.316g/cm³
• Vapor Pressure: 1.16E-06mmHg at 25°C
• Refractive Index: 1.741
• CAS DataBase Reference: 9-NITROPHENANTHRENE(CAS DataBase Reference)
• NIST Chemistry Reference: 9-NITROPHENANTHRENE(954-46-1)
• EPA Substance Registry System: 9-NITROPHENANTHRENE(954-46-1)

Safety Data

• Hazardous Substances Data: 954-46-1(Hazardous Substances Data)

Usage

General Description

9-Nitrophenanthrene is a chemical compound with the molecular formula C14H9NO2. It is a nitro derivative of phenanthrene, which is a polycyclic aromatic hydrocarbon. 9-Nitrophenanthrene is used primarily as a precursor in the synthesis of various pharmaceuticals and other organic compounds. It is also used as a research tool in the study of environmental pollutants and their impact on human health. However, it is important to note that 9-Nitrophenanthrene is considered to be hazardous, and proper precautions should be taken when handling and using this chemical to avoid any harmful effects on human health and the environment.

InChI:InChI=1/C14H9NO2/c16-15(17)14-9-10-5-1-2-6-11(10)12-7-3-4-8-13(12)14/h1-9H

Upstream product

• 85-01-8 phenanthrene 
• 7697-37-2 nitric acid 
• 108-24-7 acetic anhydride 
• 64-19-7 acetic acid 
• 68572-87-2 9-phenanthrenylboronic acid 

Downstream Products

• 165329-56-6 2H-Dibenzo[e,g]isoindole-1-carboxylic acid benzyl ester 
• 7509-44-6 10-diazophenanthren-9(10H)-one 
• 883-20-5 9-methylphenanthrene 
• 17181-05-4 (E)-9-styrylphenanthrene 
• 17181-04-3 cis-1-phenyl-2-(9-phenanthryl)ethene 
• 81593-08-0 N-9-phenanthrenylbenzamide 
• 302595-31-9 benzylidene-[9]phenanthryl-amine 
• 4235-09-0 9-(N-acetylamino)phenanthrene 
• 14140-04-6 phenanthrene-9,10-dione oxime 
• 235-93-8 phenanthro<9,10-c>pyrrole 
• 947-73-9 9-Aminophenanthrene 
• 215-64-5 dibenzo[a,c]phenacine 

Relevant articles and documents

Ipso-nitration of arylboronic acids with bismuth nitrate and perdisulfate

An efficient and one pot synthetic method of ipso-nitration of arylboronic acids has been developed. The high efficiency, general applicability, and broader substrate scope including heterocycles and functional groups make this method advantageous. Due to its simplicity, we expect to find application of this method in synthesis.

The Formation of Monomeric and Dimeric Nitro Nitrates in the Reaction of Phenanthrene with Nitrogen Dioxide; X-Ray Crystal Structure of trans-10-Nitro-9,10-dihydrophenanthren-9-yl Nitrate

Reaction of phenanthrene (1) with nitrogen dioxide in benzene solution gives the dimeric nitro nitrate (3), trans and cis nitro nitrates (7) and (8), and 9-nitro- (4), 3-nitro- (5) and 1-nitro-pnenanthrene (6).The X-ray crystal structure of the trans nitro nitrate (7) is reported.The effect of the phenanthrene (1) concentration on product yields is reported.Gas-liquid chromatography results for the nitro nitrates (3) and (7) point to difficulties in using this technique for product analyses in reactions of phenanthrene (1) with nitrogen dioxide.

Reactions of Phenanthrenes with Nitrogendioxid in UV Light

The compounds 2-7 were isolated from solutions of phenanthrene (1) and nitrogendioxide in carbon tetrachloride after irradiation with UV light having long wavelengths (λ > 290 nm).With the help of spectroscopical methods the proposed structures are derived.Radical mechanisms are proposed for these reactions. - Key words: Phenanthrene, Nitrogendioxid, UV Light