95532-30-2

Upstream product

• 32821-68-4 3-ethyl-tetrahydro-pyran-2-one 
• 76566-90-0 (+/-)-methyl (1S,3aR,4S,5R,7aS)-5-(tert-butyldiphenylsiloxy)-1-ethyl-3a,4,5,7a-tetrahydro-4-indancarboxylate 
• 76566-90-0 methyl (1S,3aR,4S,5R,7aS)-5-(tert-butyldiphenylsiloxy)-1-ethyl-3a,4,5,7a-teterahydro-4-indancarboxylate 
• 80183-16-0 methyl (2E,6S,7E,9E)-11-{[tert-butyl(diphenyl)silyl]oxy}-6-ethylundeca-2,7,9-trienoate 
• 2973-86-6 lithium thiophenoxide 
• 186581-53-3 diazomethane 
• 95671-28-6 (1S,3aR,4S,5R,7aS)-1-ethyl-3a,4,5,7a-tetrahydro-5-<(phenylthio)methyl>-4-indancarboxylic acid 
• 76566-89-7 (+/-)-1α-Ethyl-5β-(hydroxymethyl)-3aβ,4,5,7aα-tetrahydroindan-4β-carboxylic Acid γ-Lactone 
• 76566-97-7 (+/-)-(E,E)-9-<(tert-Butyldimethylsilyl)oxy>-6-ethyl-2,4-nonadien-1-ol 
• 76566-94-4 (+/-)-5-<(tert-Butyldimethylsilyl)oxy>-2-ethylpentanal 
• 76566-93-3 3-Ethyl-2-hydroxytetrahydropyran 
• 76566-98-8 C₃₃H₅₂O₂Si₂ 
• 76566-92-2 methyl 9-(tert-butylduphenylsiloxy)-6-ethyl-2,7,9-undecatrienoate 
• 76567-00-5 (5E,7E)-9-(tert-Butyl-diphenyl-silanyloxy)-4-ethyl-nona-5,7-dienal 

Downstream Products

• 95588-46-8 (+/-)-(1S,3aR,4S,5R,7aS)-1-ethyl-3a,4,5,7a-tetrahydro-5-<(phenylthio)methyl>-4-indanmethanol 
• 80109-53-1 tert-butyl<<(1S,3aR,4S,5R,7aS)-1-ethyl-3a,4,5,7a-tetrahydro-5-<(phenylsulfonyl)methyl>-4-indanyl>methoxy>dimethylsilane 
• 95532-27-7 (1S,3aR,4S,5R,7aS)-1-ethyl-3a,4,5,7a-tetrahydro-5-<(phenylsulfonyl)methyl>-4-indanmethanol 
• 80109-54-2 (R)-2-((2R,5S,6R)-6-{(E)-4-Benzenesulfonyl-4-[(1S,3aR,4S,5R,7aS)-4-(tert-butyl-dimethyl-silanyloxymethyl)-1-ethyl-2,3,3a,4,5,7a-hexahydro-1H-inden-5-yl]-1-ethyl-but-1-enyl}-5-methyl-tetrahydro-pyran-2-yl)-propionic acid methyl ester 
• 80109-52-0 (1S,3aR,4S,5R,7aS)-1-ethyl-3a,4,5,7a-tetrahydro-5-<(phenylthio)methyl>-4-indanmethanol 
• 66513-28-8 antibiotic X-14547 A 
• 80109-54-2 (R)-2-((2R,5S,6R)-6-{(E)-4-Benzenesulfonyl-4-[(1R,3aS,4R,5S,7aR)-4-(tert-butyl-dimethyl-silanyloxymethyl)-1-ethyl-2,3,3a,4,5,7a-hexahydro-1H-inden-5-yl]-1-ethyl-but-1-enyl}-5-methyl-tetrahydro-pyran-2-yl)-propionic acid methyl ester 
• 95588-48-0 (+/-)-tert-butyl<<(1S,3aR,4S,5R,7aS)-1-ethyl-3a,4,5,7a-tetrahydro-5-<(phenylsulfonyl)methyl>-4-indanyl>methoxy>dimethylsilane 
• 95588-47-9 (+/-)-(1S,3aR,4S,5R,7aS)-1-ethyl-3a,4,5,7a-tetrahydro-5-<(phenylsulfonyl)methyl>-4-indanmethanol 

Relevant academic research and scientific papers

Total Synthesis of Ionophore Antibiotic X-14547A

A highly stereocontrolled and convergent total synthesis of optically active ionophore antibiotic X-14547A (1) was designed and carried out.Degradative reactions led to the key intermediates 3 and 6, which served as convenient comparison stages.The tetrah