95556-56-2Relevant academic research and scientific papers
Rhodium-Catalyzed Room Temperature C-C Activation of Cyclopropanol for One-Step Access to Diverse 1,6-Diketones
Ghosh, Asit,Pati, Bedadyuti Vedvyas,Ravikumar, P. C.
supporting information, (2020/04/02)
A rhodium-catalyzed room temperature C-C activation of cyclopropanol has been demonstrated for the single-step synthesis of a range of electronically and sterically distinct 1,6-diketones. This reaction proceeds efficiently in shorter reaction time following a highly atom-economical pathway. To illustrate the synthetic potential of 1,6-diketones, aldol and macrocyclization reactions have been successfully demonstrated. Preliminary mechanistic studies revealed the involvement of nonradical pathways.
Novel synthetic method for symmetric diketones from benzimidazolium salts and bis-Grignard reagents
Jiang,Shi
, p. 4137 - 4142 (2007/10/03)
The reaction of 2-substituted benzimidazolium salts and bis-Grignard reagents is reported and a novel method for the preparation of symmetric diketones from carboxylic acid is provided.
Debenzotriazolylation of α-benzotriazolyl ketones with samarium diiodide
Katritzky, Alan R.,Wang, Junquan,Henderson, Scott A.
, p. 1567 - 1574 (2007/10/03)
Removal of the benzotriazolyl moiety of α-benzotriazolyl ketones by samarium diiodide at room temperature to give the corresponding ketones in good yields is described.
The synthesis of diketones from bis-benzimidazole methiodide salts
Shi, Zhen,Gu, Huan,Hue, Li-Li
, p. 3174 - 3178 (2007/10/03)
The conversion of readily available bis-benzimidazole methiodide salts to symmetrical diketones is reported.The scope and limitations of this synthesis are discussed.
ON THE SYNTHESIS OF 1,n-DIKETONES USING MONO-SUBSTITUTED DERIVATIVES OF TOSYLMETHYL ISOCYANIDE
Leusen, Albert M. van,Oosterwijk, Roelof,Echten, Erik van,Leusen, Daan van
, p. 50 - 53 (2007/10/02)
A new method is described for the synthesis of symmetrical and unsymmetrical diketones.Particularly good results are obtained in the synthesis of 1,6- and 1,5-diketones.Procedures are reported for 1,2-diketones.The moderate results obtained for 1,4-diketones and the lack of success for 1,3-diketones are discussed.
