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95687-85-7

8-Azabicyclo[3.2.1]octane, 8-benzoyl- is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

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  • 95687-85-7 Structure

  • Basic information

    1. Product Name: 8-Azabicyclo[3.2.1]octane, 8-benzoyl-
    2. Synonyms:
    3. CAS NO:95687-85-7
    4. Molecular Formula: C14H17NO
    5. Molecular Weight: 215.295
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 95687-85-7.mol

  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: N/A
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: 8-Azabicyclo[3.2.1]octane, 8-benzoyl-(CAS DataBase Reference)
    10. NIST Chemistry Reference: 8-Azabicyclo[3.2.1]octane, 8-benzoyl-(95687-85-7)
    11. EPA Substance Registry System: 8-Azabicyclo[3.2.1]octane, 8-benzoyl-(95687-85-7)

  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 95687-85-7(Hazardous Substances Data)

95687-85-7 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 95687-85-7 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 9,5,6,8 and 7 respectively; the second part has 2 digits, 8 and 5 respectively.
Calculate Digit Verification of CAS Registry Number 95687-85:
(7*9)+(6*5)+(5*6)+(4*8)+(3*7)+(2*8)+(1*5)=197
197 % 10 = 7
So 95687-85-7 is a valid CAS Registry Number.

95687-85-7Relevant articles and documents

Catalyst-Controlled Diastereoselective Synthesis of Cyclic Amines via C-H Functionalization

Munnuri, Sailu,Adebesin, Adeniyi Michael,Paudyal, Mahesh P.,Yousufuddin, Muhammed,Dalipe, Alfonso,Falck, John R.

supporting information, p. 18288 - 18294 (2017/12/27)

Reliable regio- and stereochemical techniques applicable to nonactivated aliphatic systems remain largely elusive due to the challenges of discriminating between multiple, relatively strong sp3 C-H bonds whose chemical behavior often differ onl

Synthesis of bridged azabicyclic compounds using radical translocation reactions of 1-(o-halogenobenzoyl)-2-(prop-2-enyl)-and -(prop-2-ynyl)-piperidines

Ikeda, Masazumi,Kugo, Yasuhiro,Sato, Tatsunori

, p. 1819 - 1824 (2007/10/03)

Methyl 1-(o-bromobenzoyl)-2-(prop-2-enyl)piperidine-2-carboxylate 8a, upon treatment with tributyltin hydride in the presence of azoisobutyronitrile in boiling toluene gave regioselectively the 8-azabicyclo[3.2.1]octane 14a (a 5-exo cyclisation product) in quantitative yield as a diastereomeric mixture (66:34). 1-(o-Bromobenzoyl)-2-(prop-2-enyl)piperidine 13 also gave the 8-azabicyclo-[3.2.1]octane 16 (75% as a diastereomeric mixture), along with the pyrido[2,1-a]isoindolone 17 (10%) and the simple reduction product 18 (5%). 1-(o-Iodobenzoyl)-2-[3-(trimethylsilyl)prop-2-ynyl]piperidine 23 afforded, in addition to the pyrido[2,1-a]isoindolone 25 (18%), the 8-azabicyclo-[3.2.1]octane 24 (75%) which was converted into the 6-oxo derivative 27. For comparison, the behaviour of the azetidine congener 31 was also examined.

Synthesis of bridged azabicyclic compounds using raducal translocation reactions of 1-(o-bromobenzoyl)-2-(prop-2-enyl)pyrrolidines

Sato, Tatsunori,Kugo, Yasuhiro,Nakaumi, Erina,Ishibashi, Hiroyuki,ikeda, Masazumi

, p. 1801 - 1810 (2007/10/02)

A new synthesis of the 7-azabicycloheptane and 8-azabicyclooctane systems is described in which α-acylamino radicals generated from 1-(o-bromobenzoyl-2-(prop-2-enyl)pyrrolidines by a Bu3SnH-mediated radical translocation reaction are cyclised.Treatment of methyl 1-(o-bromobenzoyl)-2-(prop-2-enyl)pyrrolidine-2-carboxylate 3a with Bu3SnH in the presence of a catalytic amount of azoisobutyronitrile in boiling toluene gave the 7-azabicycloheptane 4a (a 5-exo cyclisation product) and the 8-azabicyclooctane 5a (a 6-endo product) (30percent), together with the reduction product 6a (12percent).The geriochemistry (5-exo/6-endo) of this cyclisation could be controlled by the introduction of a substituent on the prop-2-enyl group.The substituent(s) at the 2- and/or 4-position(s) of the pyrrolidine ring were found to play an important role in this cyclisation.

SYNTHESIS OF 7-AZABICYCLOHEPTANE AND 8-AZABICYCLOOCTANE SYSTEMS USING RADICAL CYCLIZATION

Sato, Tatsunori,Mori, Tomiyo,Sugiyama, Tadakatsu,Ishibashi, Hiroyuki,Ikeda, Masazumi

, p. 245 - 248 (2007/10/02)

A new method for the synthesis of the titled systems using cyclization of the α-acylamino radicals generated from methyl N-(o-bromobenzoyl)-2-(prop-2-enyl)pyrrolidine-2-carboxylates and the piperidine congener by Bu3SnH-mediated radical translocation reaction is described.

A NEW SYNTHETIC ROUTE TO TROPANE ALKALOIDS. PSEUDOTROPINE AND TROPACOCAINE

Iida, Hideo,Watanabe, Yohya,Kibayashi, Chihiro

, p. 5091 - 5094 (2007/10/02)

Pseudotropine and tropacocaine have been synthesized by a facile route involving the nitroso cycloaddition followed by internal SN2 displacement.

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