95745-36-1

Upstream product

• 120-72-9 indole 
• 37973-54-9 1,1-diacetoxy-3-phenylprop-2-ene 
• 104-54-1 3-Phenylpropenol 
• 100-51-6 benzyl alcohol 
• 104-55-2 3-phenyl-propenal 

Relevant academic research and scientific papers

Organocatalytic combinatorial synthesis of quinazoline, quinoxaline and bis(indolyl)methanes

Aims and Objective: An efficient and practical procedure for the synthesis of heterocyclic compounds such as quinazolines, quinoxalines and bis(indolyl)methanes was developed using 3,5-bis(trifluoromethyl) phenyl ammonium hexafluorophosphate (BFPHP) as a novel organocatalyst. Materials and Methods: All of the obtained products are known compounds and identified by IR, 1HNMR, 13CNMR and melting points. Result: Various products were obtained in good to excellent yields under reaction conditions Conclusion: The BFPHP organocatalyst demonstrates a novel class of non-asymmetric organocatalysts, which has gained much attention in green chemistry.

Chemoselective synthesis of bis(indolyl)methanes using sulfonic acid-functionalized chitosan

Abstract: Herein, we describe the electrophilic substitution reaction of indole with aldehydes and ketone using sulphonic acid functional group containing chitosan for the synthesis of bis(indolyl)methanes. The reaction is chemoselective affording a produ

Green and efficient synthesis of aryl/alkylbis(indolyl)methanes using Expanded Perlite-PPA as a heterogeneous solid acid catalyst in aqueous media

Expanded Perlite-Polyphosphoric acid (EP-PPA) as a novel, efficient, recyclable and eco-benign heterogeneous catalyst has been applied for the green and rapid synthesis of aryl/alkylbis(indolyl)methanes, in water, in good to excellent yields. The catalyst

Mn(pbdo)2Cl2/MCM-41 as a green catalyst in multi-component syntheses of some heterocycles

Mn(pbdo)2Cl2/MCM-41 as a solid acid catalyst was used as an efficient, green, reusable catalyst for an improved and rapid one-pot multi-component reaction in the synthesis of bis-(4-hydroxycoumarin), bis(indolyl)methane, and 4H-benzo

Starch as a green source for Fe3O4@carbon core-shell nanoparticles synthesis: A support for 12-tungstophosphoric acid, synthesis, characterization, and application as an efficient catalyst

12-Tungstophosphoric acid (PW) immobilized on carbon-coated Fe3O4 nanoparticles (Fe3O4@C-PW) was prepared through a combination of hydrothermal and chemical co-precipitation. The intermediate carbon layer, which was produced from starch as a green material, protects the magnetic core and also improves the dispersion and catalytic activity of the nanoparticles. Characterization of this catalyst was investigated by high resolution transmission electron microscopy (HRTEM), Fourier transform infrared spectroscopy (FT-IR), vibrating sample magnetometry, and the acidic properties were studied by NH3-temperature programmed desorption and potentiometric titration. The HRTEM image showed that the catalyst had a well-defined core-shell structure with an average particle size of 50 nm. The characterization data derived from FT-IR reveal that basic structure and geometry of the Keggin anion are preserved after synthesis of Fe3O4@C-PW. The as-prepared Fe3O4@C-PW was used as a nanocatalyst for the synthesis of various bis(indolyl)methanes and β-functionalized indoles in water. The catalyst can be recovered simply using an external magnetic field and reused several times without appreciable loss of its catalytic activity.

Synthesis and characterization of Polyindole and its catalytic performance study as a heterogeneous catalyst

The catalytic performance study of polyindole as a heterogeneous catalyst is reported for the synthesis of 3,3'-arylmethylene-bis-1H-Indole derivatives using various substituted aldehydes and indole under reflux reaction condition with good to excellent y

Succinimidinium hydrogensulfate ([H-Suc]HSO4) as a new, green and efficient ionic liquid catalyst for the synthesis of tetrahydrobenzimidazo[2,1-b]quinazolin-1(2H)-one, 1-(benzothiazolylamino)phenylmethyl-2-naphthol, 1, 8-dioxo-octahydroxanthen

In this work, succinimidinium hydrogensulfate ([H-Suc]HSO4), a newly reported Br?nsted acidic ionic liquid, is used as an efficient and reusable catalyst in the synthesis of tetrahydrobenzimidazo[2,1-b]quinazolin-1(2H)-ones, 1-(benzothiazolylam

A domino electro-oxidative synthesis of 3,3′-bis(indolyl)methane nanoparticles

An effective route for electro-oxidative synthesis of 3,3′-bis(indolyl)methane nanoparticles has been described via a domino multi-component reaction between various alcohols and indole derivatives in an undivided cell under constant potential conditions in CH3CN at room temperature. The mechanistic aspect of this electro-oxidative condensation has also been studied by UV-Vis spectra and cyclic voltammograms. The nanostructure of the products has been confirmed by scanning electron microscopy. Graphical abstract: [Figure not available: see fulltext.]

Development of Br?nsted-lewis acidic solid catalytic system of 3-methyl-1-sulfonic acid imidazolium transition metal chlorides for the preparation of bis(indolyl)methanes

Three new heterogeneous catalysts of 3-methyl-1-sulfonic acid imidazolium transition metal chlorides [Msim][X] (where X=[FeCl4]-, [ZnCl3]-,[CuCl2]-) were synthesized containing both Lewis and Br?nsted acidic sites. These s

Development of Br?nsted-Lewis acidic solid catalytic system of 3-methyl-1-sulfonic acid imidazolium transition metal chlorides for the preparation of bis(indolyl)methanes

Three new heterogeneous catalysts of 3-methyl-1-sulfonic acid imidazolium transition metal chlorides [Msim][X] (where X = [FeCl4]-, [ZnCl3]-, [CuCl2]-) were synthesized containing both Lewi