PtCl₂CO(C₆H₅)2PCH₂SCH₃

Base Information

• Chemical Name: PtCl₂CO(C₆H₅)2PCH₂SCH₃
• CAS No.: 95823-89-5
• Molecular Formula: C₁₅H₁₅Cl₂OPPtS
• Molecular Weight: 540.309
• Mol file: 95823-89-5.mol

Synonyms:

Chemical Property of PtCl₂CO(C₆H₅)2PCH₂SCH₃

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of PtCl₂CO(C₆H₅)2PCH₂SCH₃

There total 4 articles about PtCl₂CO(C₆H₅)2PCH₂SCH₃ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 62.0%

dichloro(1,5-cyclooctadiene)platinum(ll) (12080-32-9) + carbon monoxide (201230-82-2) + diphenylphosphino(methylthio)methane (13119-14-7) → PtCl2CO(C6H5)2PCH2SCH3 (95823-89-5)

Guidance literature:

In dichloromethane; byproducts: C8H12; Carbon monoxide is bubbled through a CH2Cl2 soln. of PtCl2(cod) for 30 min. Ph2PCH2SCH3 dissolved in CH2Cl2, is added slowly, and the mixt. is stirred for 30 min.; The soln. is reduced in vol., and addn. of ether produces a white ppt., which was filtered and air dried. Elem. anal.;

DOI:10.1016/S0022-328X(00)99464-6

Reference yield:

(platinum(Cl)(Ph2PCH2SCH3)2)(rhodium(Cl)2(CO)2) (123455-00-5) → PtCl2CO(C6H5)2PCH2SCH3 (95823-89-5) + dirhodium(Cl)2(CO)2(μ-Ph2PCH2SCH3)2 (114630-32-9)

Guidance literature:

In chloroform-d1; byproducts: CO; warming of soln. from -50°C to ambient temp., standing for 1 h (under Ar);

DOI:10.1016/0022-328X(89)85416-6

Reference yield:

di(rhodium)tetracarbonyl dichloride + cis-platinum(Cl)2(Ph2PCH2SCH3)2 (95787-29-4,95840-67-8) → PtCl2CO(C6H5)2PCH2SCH3 (95823-89-5) + Rh2Cl2(CO)2((C6H5)2PCH2SCH3)2 (114630-32-9)

Guidance literature:

In chloroform-d1; The two complexes are allowed to react in CDCl3 soln.; The react. is monitored by (31)P-NMR.;

DOI:10.1016/S0022-328X(00)99464-6

upstream raw materials:

cis-platinum(Cl)2(Ph₂PCH₂SCH₃)2

(platinum(Cl)(Ph₂PCH₂SCH₃)2)(rhodium(Cl)2(CO)2)

dichloro(1,5-cyclooctadiene)platinum(ll)

carbon monoxide

Downstream raw materials:

PtCl₂((C₆H₅)2PCH₂SCH₃)