95827-00-2

Basic information

• Product Name: 3-Buten-1-one, 1-(4-chlorophenyl)-
• CAS NO: 95827-00-2
• Molecular Formula: C10H9ClO
• Molecular Weight: 180.634
• Mol File: 95827-00-2.mol
• Article Data: 30

Chemical Properties

• CAS DataBase Reference: 3-Buten-1-one, 1-(4-chlorophenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: 3-Buten-1-one, 1-(4-chlorophenyl)-(95827-00-2)
• EPA Substance Registry System: 3-Buten-1-one, 1-(4-chlorophenyl)-(95827-00-2)

Safety Data

• Hazardous Substances Data: 95827-00-2(Hazardous Substances Data)

Upstream product

• 122-01-0 4-chloro-benzoyl chloride 
• 137626-45-0 allyltetrabutylstiborane 
• 106-95-6 allyl bromide 
• 873-76-7 para-Chlorobenzyl alcohol 
• 104-88-1 4-chlorobenzaldehyde 
• 14506-33-3 1-(4-chlorophenyl)but-3-en-1-ol 
• 7393-43-3 tetraallyl tin 
• 762-72-1 allyl-trimethyl-silane 
• 762-73-2 trimethyl(allyl)stannane 
• 3457-46-3 4,4'-dichlorobenzil 
• 10364-95-1 1-(4-chloro-benzoyl)-1H-imidazole 
• 2622-05-1 allylmagnesium bromide 
• 13014-48-7 4-chlorobenzoyl cyanide 

Downstream Products

• 95826-96-3 (E)-1-(4-chlorophenyl)-2-buten-1-one 
• 1023294-62-3 1-(4-chlorophenyl)but-3-en-1-one oxime 
• 1431380-79-8 5-(bromomethyl)-3-(4-chlorophenyl)-4,5-dihydroisoxazole 
• 62353-39-3 3-(4-chlorophenyl)-5-(chloromethyl)-4,5-dihydroisoxazole 
• 136146-93-5 p-Chlorophenyl(3-bromo-2-methoxypropyl)ketone 
• 1420031-33-9 (S)-5-benzyl-3-(4-chlorophenyl)-4,5-dihydroisoxazole 
• 1158557-23-3 5-benzyl-3-(4-chlorophenyl)-4,5-dihydroisoxazole 
• 1155956-75-4 (E)-1-(4-chlorophenyl)-4-hydroxybut-2-en-1-one 

Relevant articles and documents

Visible Light-Promoted Recyclable Carbon Nitride-Catalyzed Dioxygenation of β,γ-Unsaturated Oximes

A visible-light-induced dioxygenation of β,γ-unsaturated oximes for the synthesis of diverse useful isoxazolines bearing a hydroxyl moiety was developed by employing graphitic carbon nitride (g-C3N4) as a heterogeneous photocatalyst under an air atmosphere. Noted that, the eminent advantages of this metal-free protocol include step economy, easy operation, a recyclable photocatalyst, external reductant-/oxidant-free and mild reaction conditions. Additionally, mechanistic studies indicated hydroxyl radical was generated under the photocatalysis of g-C3N4.

Ni-Catalyzed 1,2-Diarylation of Alkenyl Ketones: A Comparative Study of Carbonyl-Directed Reaction Systems

A nickel-catalyzed 1,2-diarylation of alkenyl ketones with aryl iodides and arylboronic esters is reported. Ketones with a variety of substituents serve as effective directing groups, offering high levels of regiocontrol. A representative product is diversified into a wide range of useful products that are not readily accessible via existing 1,2-diarylation reactions. Preliminary mechanistic studies shed light on the binding mode of the substrate, and Hammett analysis reveals the effect of electronic factors on initial rates.

Enantioselective Synthesis of Isoxazolines Enabled by Palladium-Catalyzed Carboetherification of Alkenyl Oximes

Reported here is a highly efficient Pd/Xiang-Phos catalyzed enantioselective carboetherification of alkenyl oximes with either aryl or alkenyl halides, delivering various chiral 3,5-disubstituted and 3,5,5-trisubstituted isoxazolines in good yields with u