95903-96-1Relevant academic research and scientific papers
SYNTHESIS AND PROPERTIES OF TRIETHYLBENZYLAMMONIUM ALKOXIDES. REACTIVITY IN ELIMINATION AND NUCLEOPHILIC SUBSTITUTION REACTIONS
Shavanov, S. S.,Tolstikov, G. A.,Shutenkova, T. V.,Ryabova, N. A.,Filippova, S. A.
, p. 643 - 647 (2007/10/02)
Triethylbenzylammonium alkoxides exhibit high reactivity during the elimination of hydrogen chloride from polychloroalkanes and can also be used in the synthesis of ethers from halogenoalkanes.Quaternary ammonium salts do not form tetraalkylammonium or trialkylbenzylammonium alkoxides under the influence of a concentrated aqueous solution of sodium hydroxide in the presence of alcohols.
CATALYSIS OF LIQUID-PHASE DEHYDROCHLORINATION OF 1,1,2-TRICHLOROETHANE.
Shavanov,Tolstikov,Viktorov,Shutenkova
, p. 139 - 141 (2007/10/02)
Experiments show that vinylidene chloride can be obtained in virtually quantitative yield by the use of triethylbenzylammonium alkoxides as catalysts of 1,1,2-trichloroethane dehydrochlorination. Catalyst anions containing an unsaturated carbon bond in the position relative to oxygen increase catalyst activity. The catalyst is present in the organic phase and is not transferred from one phase into the other.
