96-08-2

Basic information

• Product Name: 1-METHYL-4-(2-METHYLOXIRANYL)-7-OXABICYCLO[4.1.0]HEPTANE
• Synonyms: 1-METHYL-4-(2-METHYLOXIRANYL)-7-OXABICYCLO[4.1.0]HEPTANE;1-METHYL-4-(1-METHYLEPOXYETHYL)-7-OXABICYCLO[4.1.0]HEPTANE;CAJEPUTENE DIOXIDE;LIMONENE DIOXIDE;CINENE DIOXIDE;Dipentene dioxide;P-MENTHA-1,8-DIENE DIOXIDE;1,2,8,9-Diepoxylimonene
• CAS NO: 96-08-2
• Molecular Formula: C₁₀H₁₆O₂
• Molecular Weight: 168.23
• EINECS: 202-475-1
• Mol File: 96-08-2.mol
• Article Data: 111

Chemical Properties

• Boiling Point: 237.18°C (rough estimate)
• Flash Point: 100.4°C
• Appearance: clear to light yellow liquid
• Density: 0.9607 (rough estimate)
• Vapor Pressure: 0.0431mmHg at 25°C
• Refractive Index: 1.4480 (estimate)
• CAS DataBase Reference: 1-METHYL-4-(2-METHYLOXIRANYL)-7-OXABICYCLO[4.1.0]HEPTANE(CAS DataBase Reference)
• NIST Chemistry Reference: 1-METHYL-4-(2-METHYLOXIRANYL)-7-OXABICYCLO[4.1.0]HEPTANE(96-08-2)
• EPA Substance Registry System: 1-METHYL-4-(2-METHYLOXIRANYL)-7-OXABICYCLO[4.1.0]HEPTANE(96-08-2)

Safety Data

• Hazardous Substances Data: 96-08-2(Hazardous Substances Data)

Usage

General Description

1-METHYL-4-(2-METHYLOXIRANYL)-7-OXABICYCLO[4.1.0]HEPTANE, also known as Anethole, is a chemical compound with the molecular formula C11H16O. It is a bicyclic organic compound that contains a seven-membered ring with one oxygen atom. Anethole is commonly found in essential oils, such as anise and fennel, and is responsible for their distinct aroma and flavor. It is used as a flavoring agent in food and beverages and also has potential medicinal properties, including antimicrobial and antioxidant effects. Anethole has a sweet, aromatic taste and is often used in the production of licorice-flavored products and herbal remedies.

InChI:InChI=1/C10H16O2/c1-9-4-3-7(5-8(9)12-9)10(2)6-11-10/h7-8H,3-6H2,1-2H3

Upstream product

• 5989-54-8 (-)-(S)-limonene 
• 203719-53-3 (-)-limonene oxide 
• 5989-27-5 D-limonene 
• 138-86-3 limonene. 
• 6909-30-4 (1S,2R,4R)-limonene-1,2-epoxide 
• 4680-24-4 cis-(R)-limonene oxide 
• 1195-92-2 (4R)-limonene 1,2-epoxide 
• 105-87-3 3,7-dimethyl-2E,6-octadien-1-yl acetate 
• 1195-92-2 Limonene oxide 
• 184488-93-5 (R)-8,9-limonene oxide 
• 28098-67-1 (R)-2-methyl-2-((R)-4-methylcyclohex-3-enyl)oxirane 
• 28098-68-2 (S)-2-methyl-2-((R)-4-methylcyclohex-3-enyl)oxirane 

Downstream Products

• 18679-48-6 2-Hydroxycineole 
• 54145-81-2 1,2-epoxy-8-hydroxy-p-menthane 
• 5581-31-7 4-(1,2-dihydroxypropan-2-yl)-1-methylcyclohexane-1,2-diol 
• 95602-94-1 (6S,1'S)-6-(1'-hydroxy-1',5'-dimethyl-4'-hexenyl)-3-methyl-2-cyclohexenone 
• 106145-00-0 (6S,1'R)-6-(1'-hydroxy-1',5'-dimethyl-4'-hexenyl)-3-methyl-2-cyclohexenone 
• 106144-98-3 (R)-4-(1-Hydroxy-1,5-dimethyl-hex-4-enyl)-1-methyl-2-phenylselanyl-cyclohexanol 
• 106144-99-4 (R)-4-(1-Hydroxy-1,5-dimethyl-hex-4-enyl)-1-methyl-cyclohex-2-enol 
• 110654-86-9 (S)-5-(1-Hydroxy-1,5-dimethyl-hex-4-enyl)-2-methyl-2-phenylselanyl-cyclohexanol 
• 110654-86-9 (R)-5-(1-Hydroxy-1,5-dimethyl-hex-4-enyl)-2-methyl-2-phenylselanyl-cyclohexanol 
• 106144-98-3 (1R,2R,4S)-4-(1'-hydroxy-1',5'-dimethyl-4'-hexenyl)-1-methyl-2-phenylselenocyclohexanol 
• 106144-99-4 (1'S,4'R)-2-(4'-hydroxy-4'-methyl-2'-cyclohexenyl)-6-methyl-5-hepten-2-ol 
• 110715-85-0 (6R,1'S)-epi-hernandulcin 
• 110715-84-9 (-)-hernandulcin 
• 110654-87-0 (1'S,3'R)-2-(3'-hydroxy-4'-methylcyclohexenyl)-6-methyl-5-hepten-2-ol 

Relevant articles and documents

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Aldehyde-catalyzed epoxidation of unactivated alkenes with aqueous hydrogen peroxide

The organocatalytic epoxidation of unactivated alkenes using aqueous hydrogen peroxide provides various indispensable products and intermediates in a sustainable manner. While formyl functionalities typically undergo irreversible oxidations when activating an oxidant, an atropisomeric two-axis aldehyde capable of catalytic turnover was identified for high-yielding epoxidations of cyclic and acyclic alkenes. The relative configuration of the stereogenic axes of the catalyst and the resulting proximity of the aldehyde and backbone residues resulted in high catalytic efficiencies. Mechanistic studies support a non-radical alkene oxidation by an aldehyde-derived dioxirane intermediate generated from hydrogen peroxide through the Payne and Criegee intermediates.

Modification of MnFe2O4 surface by Mo (VI) pyridylimine complex as an efficient nanocatalyst for (ep)oxidation of alkenes and sulfides

In this current paper, we report a new type of heterogeneous molybdenum (+6) complex, prepared by covalent grafting of cis-dioxo?molybdenum (VI) pyridylimine complex on the surface of MnFe2O4 nanoparticles (NP) and characterized using various physicochemical techniques. The recyclable prepared nanocatalyst was tested for sulfoxidation of sulfides and epoxidation of alkenes under solvent-free condition. The catalyst exhibited high turnover frequency for the oxidization of cyclooctene and cyclohexene (10,850 h?1) and thioanisole and dimethyl sulfide (41,250 h?1). The synthesized catalyst was found highly efficient, retrievable and eco-friendly catalyst for the (ep)oxidation of alkenes and sulfides in excellent yields in a short time. Furthermore, the synthesized nanocatalyst can be reused for four runs without apparent loss of its catalytic activity in the oxidation reaction.