96093-87-7

Upstream product

• 1165952-91-9 cyclohexa-1,3-diene 
• 56239-25-9 (+/-)-2-Oxa-3-azabicyclo[2.2.2]oct-5-ene hydrochloride 
• 56239-25-9 2-Oxa-3-azabicyclo<2.2.2>oct-5-ene hydrochloride 
• 237752-48-6 2-oxa-3-azabicyclo[2.2.2]oct-5-en-3-yldiphenylphosphine oxide 
• 96093-86-6 (1R,4S)-2-Oxa-3-aza-bicyclo[2.2.2]oct-5-en-3-yl-phenyl-methanone 

Downstream Products

• 77803-78-2 cis-1-Acetamido-2-cyclohexen-4-ylacetat 
• 77803-79-3 N-(cis-4-Hydroxy-2-cyclohexen-1-yl)acetamid 
• 131244-20-7 (+/-)-3r-isopropyldimethylsiloxy-6c-phthalimidocyclohexene 
• 131244-22-9 (+/-)-4c-phthalimidocyclohex-2-enyl trichloroacetimidate 
• 131244-27-4 (+/-)-2c-acetamido-4c-phthalimidocyclohexyl acetate 
• 131244-36-5 (+/-)-3t-hydroxy-6t-phthalimido-2t-trichloroacetamidocyclohexyl acetate 
• 131244-25-2 (+/-)-3t-iodo-4c-phthalimido-2c-trichloracetamidocyclohexyl acetate 
• 73237-85-1 (+/-)-2c,4c-diaminocyclohexan-1r-ol 
• 784106-45-2 (+/-)-2c,4c-diaminocyclohexane-1r,3t-diol 
• 20021-57-2 r-1-Acetamidocyclohexan-t-2,t-3,c-4-triyltriacetat 
• 77803-85-1 r-1-Acetamido-c-2,c-3-epoxy-c-4-cyclohexylacetat 
• 77803-82-8 c-2-Acetoxy-t-3-brom-c-4-hydroxy-r-1-cyclohexylammoniumbromid 
• 77803-80-6 r-1-Acetamido-t-3-brom-c-2-hydroxy-c-4-cyclohexylacetat 
• 77803-83-9 N-(t-3-Brom-c-2,c-4-dihydroxy-r-1-cyclohexyl)acetamid 

Relevant academic research and scientific papers

Hetero-Diels-Alder reaction of phosphinyl and phosphonyl nitroso alkenes with conjugated dienes: An aza-Cope rearrangement

Phosphorylated nitroso alkenes react with cyclic dienes such as cyclopentadiene or cyclohexadiene to afford hetero Diels-Alder-type cycloadducts where the nitroso alkene participates as dienophile component and the cyclic olefin acts as the 4π-electron (diene) system. Subsequent aza-Cope rearrangement affords highly functionalized 5,6-dihydro-4H-1,2-oxazines. Conversely, the reaction of TMS-substituted cyclopentadiene (dienophile) with nitroso alkenes as heterodienes leads directly to bicyclic 1,2-oxazines. Theoretical studies are in agreement with the experimental results and with the new aza-Cope rearrangement proposed.

THE MICROBIAL REDUCTIVE SPLITTING OF THE N-O BOND OF DIHYDROOXAZINES; AN ALTERNATIVE TO THE CHEMICAL REDUCTION

In the presence of artificial mediators many bacteria reductively split the N-O bond of dihydrooxazines in a chemoselective way if hydrogen is used as an electron source.The yields as determined by HPLC are almost quantitative i.e. considerably better tha

ASYMMETRIC DIELS - ALDER REACTIONS WITH α-CHLORONITROSO COMPOUNDS - I. APPLICATION OF α-CHLORONITROSO EPIANDROSTERONE IN SYNTHESIS

The Diels - Alder reaction of 1,3-cyclohexadiene (9) with the enantiomerically pure α-chloronitroso compound 8, synthesized from epiandrosterone (7a), gives the adduct 10a with 1-(R),4-(S) configuration in 69 percent chemical yield and >=95 percent enantiomeric excess.

Polyhydroxyamino Compounds via Diene Synthesis with Nitroso Compounds, IV. - Preparation and Stereochemistry of Dideoxyinosamine Derivatives

The general method for the synthesis of polyhydroxy amines by Diels-Alder reactions with a nitroso compound, reduction of the adduct with cleavage of the N - O bond and hydroxylation of the remaining C = C -double bond, can also be realized with α-chloronitrosocyclohexane as dienophile, in good yield.Primary amines are synthesized in this way.