961-27-3

Usage

Uses

Used in Chemical Synthesis:
2,7-Diacetylfluorene is used as a reactant in the synthesis of (dioxaborine)fluorene derivatives. These derivatives are valuable for the development of light-emitting diodes (LEDs) due to their unique photophysical properties, which contribute to improved device performance and efficiency.
Used in Optoelectronics Industry:
In the optoelectronics industry, 2,7-Diacetylfluorene is utilized as a key component in the production of advanced materials for LEDs. Its role in creating (dioxaborine)fluorene derivatives enhances the light-emitting capabilities of these devices, making them more efficient and suitable for various applications, such as displays, lighting, and communication systems.

Upstream product

• 86-73-7 9H-fluorene 
• 75-36-5 acetyl chloride 
• 781-73-7 1-(9H-fluoren-2-yl)ethanone 
• 108-24-7 acetic anhydride 
• 75-15-0 carbon disulfide 
• 7446-70-0 aluminium trichloride 
• 98-95-3 nitrobenzene 

Downstream Products

• 39665-89-9 2,7-diacetylfluorenone 
• 39665-90-2 2,7-diethylfluorene 
• 24929-24-6 dimethyl 9-oxo-9H-fluorene-2,7-dicarboxylate 
• 213598-63-1 4,5-dinitrofluoren-9-one-2,7-dicarboxamide 

Relevant academic research and scientific papers

Design of a MOF based on octa-nuclear zinc clusters realizing both thermal stability and structural flexibility

An octa-nuclear zinc (Zn8) cluster-based two-fold interpenetrated metal-organic framework (MOF) of [(CH3)2NH2]2[Zn8O3(FDC)6]·7DMF (denoted as Zn8-as; H2FDC = 9H-fluorene-2,7-dicarboxylic acid; DMF = N,N-dimethylformamide) was synthesized by the reaction of a hard base of a curved dicarboxylate ligand (H2FDC) with the borderline acid of Zn(ii) under solvothermal conditions. Zn8-as shows significant crystal volume shrinkage upon heating, yielding a solvate-free framework of [(CH3)2NH2]2[Zn8O3(FDC)6] (Zn8-de). Zn8-de displays gated adsorption for C2H2 and type-I adsorption for CO2, attributed to the framework flexibility and the different interactions between the gas molecules and the host framework.

Alkyl-substituted bis(4-((9H-fluoren-9-ylidene)methyl)phenyl)thiophenes: weakening of intermolecular interactions and additive-assisted crystallization

Aggregation-induced emission (AIE) materials find their applications in organic optoelectronics, bio-imaging and sensors. In this work, we introduced alkyl substituents in AIE-active bis(4-((9H-fluoren-9-ylidene)methyl)phenyl)thiophene and elucidated thei

Unbridged cyclopentadienyl-fluorenyl complexes of zirconium as catalysts for homogeneous olefin polymerization

The reaction of various lithium fluorenyl compounds, Li(C13H7R1R2) (R1R2=H, alkyl or aryl) (1a-1n), with C5H5ZrCl3 leads to unbridged fluorenyl complexes of the type (C5H5)C13H7R1R2)ZrCl2 (2a-2n) which can be converted to the corresponding metallocene dimethyl complexes (3a-3e).In combination with methylaluminoxane (MAO), 2a-2n show a higher catalytic activity as homogeneous eethylene polymerization catalysts than (C5H5)2ZrCl2.Compound 2d (R1=2-Me; R2=7-Me) was charcterized by an X-ray structure analysis.Keywords: Metallocene; Fluorenyl ligands; Olefin polymerization; Zirconium

Cyclic carbonyl compounds

Certain fluorenone and anthraquinone compounds, each of which is 2-substituted by a carboxyl group or a salt, ester or optionally substituted amide thereof and each of which is optionally substituted in the 5,6-,7-or 8-position, by a second carboxyl group, salt, ester or optionally substituted amide thereof, the substitutent in the 5,6-7- or 8-position of the fluorenone compounds, also being selected from cyano, halogen, nitro, alkyl, alkoxy and acyl, are useful for the relief or prophylaxis of allergic conditions.

Cyclic carbonyl compounds

Certain fluorenone and anthraquinone compounds, each of which is 2-substituted by a carboxyl group or a salt, ester or optionally substituted amide thereof and each of which is optionally substituted in the 5,6-,7- or 8- position, by a second carboxyl group, salt, ester or optionally substituted amide thereof, the substitutent in the 5,6-7- or 8- position of the fluorenone compounds, also being selected from cyano, halogen, nitro, alkyl, alkoxy and acyl, are useful for the relief or prophylaxis of allergic conditions.