96155-57-6

Basic information

• Product Name: Ethanone, 1-(4-methoxyphenyl)-, O-acetyloxime
• CAS NO: 96155-57-6
• Molecular Formula: C11H13NO3
• Molecular Weight: 207.229
• Mol File: 96155-57-6.mol
• Article Data: 21

Chemical Properties

• CAS DataBase Reference: Ethanone, 1-(4-methoxyphenyl)-, O-acetyloxime(CAS DataBase Reference)
• NIST Chemistry Reference: Ethanone, 1-(4-methoxyphenyl)-, O-acetyloxime(96155-57-6)
• EPA Substance Registry System: Ethanone, 1-(4-methoxyphenyl)-, O-acetyloxime(96155-57-6)

Safety Data

• Hazardous Substances Data: 96155-57-6(Hazardous Substances Data)

Upstream product

• 2475-92-5 4-methoxyacetophenone oxime 
• 75-36-5 acetyl chloride 
• 100-06-1 1-(4-methoxyphenyl)ethanone 
• 108-24-7 acetic anhydride 

Downstream Products

• 41855-50-9 2,6‐bis(4‐fluorophenyl)‐4‐phenylpyridine 
• 50553-98-5 2,6‐bis(4‐methoxyphenyl)‐4‐phenylpyridine 
• 72666-43-4 2,6-bis(4-chlorophenyl)-4-phenylpyridine 
• 72666-44-5 2-(4-Chloro-phenyl)-6-(4-methoxy-phenyl)-4-phenyl-pyridine 
• 74918-94-8 2,6‐bis(4‐bromophenyl)‐4‐phenylpyridine 
• 91232-22-3 2-(4-Bromo-phenyl)-6-(4-methoxy-phenyl)-4-phenyl-pyridine 
• 580-35-8 2,4,6-triphenylpyridine 
• 74918-90-4 2-(4-Methoxyphenyl)-4,6-diphenylpyridine 
• 54095-18-0 4-(4-methoxyphenyl)-pyrimidine 
• 31562-99-9 2-(4-methoxyphenyl)imidazo[1,2-a]pyridine 
• 65964-63-8 2-(4-methoxyphenyl)-7-methyl-imidazo[1,2-a]pyridine 
• 26921-83-5 2-(4-methoxyphenyl)benzo[d]imidazo[2,1-b]thiazole 
• 16032-40-9 2-(4-methoxyphenyl)quinoline 

Relevant articles and documents

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Copper-Catalyzed Annulation of Oxime Acetates with α-Amino Acid Ester Derivatives: Synthesis of 3-Sulfonamido/Imino 4-Pyrrolin-2-ones

A copper-catalyzed annulation of oxime acetates and α-amino acid ester derivatives for the easy preparation of 4-pyrrolin-2-ones bearing a 3-amino group has been developed. This process features the oxidation of amines with oxime esters as the internal oxidant to produce the active 1,3-dinucleophilic and 1,2-dielectrophilic species concurrently. The subsequent nucleophilic cyclization realizes the efficient construction of 4-pyrrolin-2-one derivatives.

CuCl2-catalyzed N[sbnd]O bond cleavage of oxime esters: Approach to imidazoheterocycles and furo[3,2-c]chromenyl fused imidazoles

An articulate approach to a diverse set of imidazoheterocycles in good to high yields via a copper-catalyzed aza-annulation of several oxime esters with a group of 2-amino-azaarenes was developed. The above cyclization reaction probably proceeds via a single electron transfer process which embodies a new technique for creating two new C[sbnd]N bonds for imidazole ring synthesis. Gratifyingly, the implementation of this chemistry could be further stretched to the synthesis of a novel class of fused imidazoles bearing a furo[3,2-c]chromene moiety via a sequential C[sbnd]N bond formation, followed by C(sp2)-H functionalization/5-endo-dig-oxacyclization (C[sbnd]C and C[sbnd]O bonds) of in situ produced fused imidazoles with cyclic enynones in the presence of copper(II) as a π-electrophilic Lewis acid catalyst.